|
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| (2人の利用者による、間の21版が非表示) |
| 1行目: |
1行目: |
| {{DISPLAYTITLE:2PEN2101 ICP-MS}} | | {{DISPLAYTITLE:2号機X-6ペネ調査装置付着物-1(2PEN2101)/ICP-MS}} |
| {| class="wikitable sortable mw-collapsible mw-collapsed" | | {| class="wikitable mw-collapsible mw-collapsed" |
| |+更新履歴 | | |+更新履歴 |
| !width="30pt"|No | | !width="30pt"|No |
| 7行目: |
7行目: |
| !width="500pt"|内容 | | !width="500pt"|内容 |
| !width="200pt"|備考 | | !width="200pt"|備考 |
| !width="100pt"|記載者
| |
| |- | | |- |
| |1 | | |1 |
| |2022/04/25 | | |2025/3/6 |
| |新規 | | |新規 |
| |2PEN2101 ICP-MS分析結果の登録(IRID報告書より転記)。 | | |ICP-MS分析結果の掲載(出典<ref name="JAEA23a">令和3年度福島第一原子力発電所の炉内付着物サンプル等の分析,日本原子力研究開発機構,JAEA-Data/Code 2023-005.</ref>) |
| |
| | |旧ページは [[Gr1:2PEN2101(2021)ICPMS|こちら(アクセス限定:Gr1)]] |
| |原稿作成:佐々木・大西(JAEA)<br>
| |
| wiki転記:池内(JAEA)
| |
| |-
| |
| |2
| |
| |2022/11/22
| |
| |承認
| |
| | | |
| |不確かさ及び定量下限値の評価は[[Gr1:分析方法(JAEA 2021年度)|分析方法]]に移動した。
| |
| |池内(JAEA)
| |
| |-
| |
| |3
| |
| |2023/1/6
| |
| |改訂
| |
| |Zrの追加分析結果の追記に伴い、表の連番を修正した。
| |
| |
| |
| |池内(JAEA)
| |
| |}
| |
| | |
| (1)定量分析結果
| |
| 元の試料溶液中における定量分析対象核種重量 [ng] を表(共通)-1に示す。溶解した試料重量あたりの定量分析対象核種重量 [ng/g] を表(共通)-2に示す。各核種の重量表(共通)-1から求めた各元素の同位体比を表(共通)-3に示す。参考として、各元素の天然同位体組成[19]から質量比に換算した同位体比を併記している。
| |
| Cr、Fe、Ni、Mo、Ndについては、天然同位体組成に近い同位体比であった。Uについては、U-234、U-235、U-236、U-238が検出され、U-235/U-238の同位体比(0.0200±0.0006)は天然同位体比(0.0072)よりも高い値を示しており、燃料由来であることが示唆された。
| |
| | |
| {| class="wikitable"
| |
| |+表(共通)-1 ICP-MS定量分析結果(溶解液中の核種重量)
| |
| |試料
| |
| |Li-6 [ng]
| |
| |Li-7 [ng]
| |
| |B-10 [ng]
| |
| |B-11 [ng]
| |
| |Cr-52 [ng]
| |
| |Cr-53 [ng]
| |
| |Fe-56 [ng]
| |
| |Fe-57 [ng]
| |
| |Ni-60 [ng]
| |
| |Ni-61 [ng]
| |
| |Ni-62 [ng]
| |
| |Zr-90 [ng]
| |
| |Zr-91 [ng]
| |
| |Mo-95 [ng]
| |
| |Mo-97 [ng]
| |
| |Mo-98 [ng]
| |
| |Ag-107 [ng]
| |
| |Ag-109 [ng] | |
| |Cs-133 [ng]
| |
| |Nd-143 [ng]
| |
| |Nd-145 [ng]
| |
| |Nd-146 [ng]
| |
| |U-234 [ng]
| |
| |U-235 [ng]
| |
| |U-236 [ng]
| |
| |U-238 [ng]
| |
| |-
| |
| |2PEN2101
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |5E+02 ± 1E+02
| |
| |5.1E+01 ± 2E+00
| |
| |1.10E+04 ± 3E+02
| |
| |2.4E+02 ± 1E+01
| |
| |1.08E+02 ± 1E+00
| |
| |5.3E+00 ± 8E-01
| |
| |1.35E+01 ± 8E-01
| |
| |1.38E+02 ± 1E+00
| |
| |3.4E+01 ± 3E+00
| |
| |4.3E+00 ± 5E-01
| |
| |3.17E+00 ± 7E-02
| |
| |7.2E+00 ± 2E-01
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |5.7E-01 ± 9E-02
| |
| |4E-01 ± 3E-01
| |
| |9E-01 ± 1E-01
| |
| |2E-01 ± 2E-01
| |
| |1.49E+01 ± 2E-01
| |
| |2.7E+00 ± 2E-01
| |
| |7.45E+02 ± 6E+00
| |
| |-
| |
| |2PEN2102
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |6.9E+03 ± 3E+02
| |
| |1.4E+02 ± 1E+01
| |
| |3.98E+01 ± 8E-01
| |
| |1.1E+00 ± 8E-01
| |
| |3.7E+00 ± 8E-01
| |
| |2.75E+02 ± 1E+00
| |
| |6.3E+01 ± 3E+00
| |
| |5.4E+00 ± 5E-01
| |
| |3.93E+00 ± 7E-02
| |
| |7.7E+00 ± 2E-01
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |1.12E+00 ± 9E-02
| |
| |5E-01 ± 3E-01
| |
| |9E-01 ± 1E-01
| |
| |4E-01 ± 2E-01
| |
| |2.56E+01 ± 2E-01
| |
| |4.5E+00 ± 2E-01
| |
| |1.33E+03 ± 1E+01
| |
| |-
| |
| |2WEL2101A
| |
| |<LOQ
| |
| |3.31E+02 ± 2E+00
| |
| |1.04E+03 ± 1E+01
| |
| |4.0E+03 ± 1E+02
| |
| |3.42E+03 ± 6E+01
| |
| |3.79E+02 ± 1E+00
| |
| |2.35E+07 ± 1E+05
| |
| |5.23E+05 ± 1E+03
| |
| |5.00E+03 ± 1E+01
| |
| |2.11E+02 ± 1E+00
| |
| |6.91E+02 ± 1E+00
| |
| |1.81E+03 ± 1E+01
| |
| |3.91E+02 ± 3E+00
| |
| |6.8E+03 ± 1E+02
| |
| |6.73E+03 ± 8E+01
| |
| |8.70E+03 ± 1E+02
| |
| |2.94E+01 ± 3E-01
| |
| |2.7E+02 ± 2E+01
| |
| |4.58E+02 ± 5E+00
| |
| |5.47E+00 ± 9E-02
| |
| |4.0E+00 ± 3E-01
| |
| |5.8E+00 ± 1E-01
| |
| |2E+00 ± 2E+00
| |
| |1.68E+02 ± 2E+00
| |
| |2.6E+01 ± 2E+00
| |
| |8.05E+03 ± 6E+01
| |
| |-
| |
| |2WEL2101C
| |
| |<LOQ
| |
| |<LOQ
| |
| |3.28E+02 ± 1E+00
| |
| |1.4E+03 ± 1E+02
| |
| |6.3E+02 ± 6E+01
| |
| |7.2E+01 ± 1E+00
| |
| |1.93E+06 ± 1E+04
| |
| |4.35E+04 ± 1E+02
| |
| |6.4E+02 ± 1E+01
| |
| |3.2E+01 ± 1E+00
| |
| |9.08E+01 ± 3E-01
| |
| |1.29E+02 ± 1E+00
| |
| |3.2E+01 ± 3E+00
| |
| |4.1E+02 ± 1E+01
| |
| |3.62E+02 ± 8E+00
| |
| |5.3E+02 ± 1E+01
| |
| |5.0E+00 ± 3E-01
| |
| |9.33E+01 ± 1E-01
| |
| |5.8E+01 ± 5E+00
| |
| |5.4E-01 ± 9E-02
| |
| |4E-01 ± 3E-01
| |
| |1.2E+00 ± 1E-01
| |
| |<LOQ
| |
| |1.22E+01 ± 2E-01
| |
| |2.0E+00 ± 2E-01
| |
| |5.92E+02 ± 6E+00
| |
| |-
| |
| |2WEL2102A
| |
| |<LOQ
| |
| |<LOQ
| |
| |7.35E+02 ± 1E+00
| |
| |2.9E+03 ± 1E+02
| |
| |7.57E+03 ± 6E+01
| |
| |8.30E+02 ± 1E+00
| |
| |5.27E+07 ± 1E+05
| |
| |1.17E+06 ± 1E+04
| |
| |4.28E+03 ± 1E+01
| |
| |1.75E+02 ± 1E+00
| |
| |5.71E+02 ± 1E+00
| |
| |<LOQ
| |
| |<LOQ
| |
| |1.5E+02 ± 1E+01
| |
| |9.6E+01 ± 8E+00
| |
| |2.4E+02 ± 1E+01
| |
| |1.30E+01 ± 3E-01
| |
| |1.24E+01 ± 1E-01
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |-
| |
| |2WEL2103A
| |
| |<LOQ
| |
| |<LOQ
| |
| |2.87E+02 ± 1E+00
| |
| |1.1E+03 ± 1E+02
| |
| |5.2E+02 ± 6E+01
| |
| |6.4E+01 ± 1E+00
| |
| |1.07E+07 ± 1E+05
| |
| |2.31E+05 ± 3E+03
| |
| |1.54E+02 ± 1E+00
| |
| |6.6E+00 ± 8E-01
| |
| |2.24E+01 ± 8E-01
| |
| |<LOQ
| |
| |<LOQ
| |
| |6.8E+00 ± 5E-01
| |
| |3.52E+00 ± 7E-02
| |
| |1.10E+01 ± 2E-01
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |4E-01 ± 1E-01
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |-
| |
| |} | | |} |
|
| |
|
| {| class="wikitable"
| | ==定量分析結果== |
| |+表(共通)-2 ICP-MS定量分析結果(溶液に移行した各試料単位重量あたりの核種重量)
| | : 定量分析結果を別ページ[[Results of ICP-MS-2021-JAEA#定量分析結果|ICP-MS測定結果(JAEA 2021年度 受入サンプル共通)]]に示した。 |
| |試料
| | : 2PEN2101では、Cr、Fe、Ni、Mo、Ndについては、天然同位体組成に近い同位体比であった。Uについては、U-234、U-235、U-236、U-238が検出され、U-235/U-238の同位体比(0.0200±0.0006)は天然同位体比(0.0072)よりも高い値を示しており、燃料由来であることが示唆された。 |
| |Li-6 [ng/g]
| |
| |Li-7 [ng/g]
| |
| |B-10 [ng/g]
| |
| |B-11 [ng/g]
| |
| |Cr-52 [ng/g]
| |
| |Cr-53 [ng/g]
| |
| |Fe-56 [ng/g]
| |
| |Fe-57 [ng/g]
| |
| |Ni-60 [ng/g]
| |
| |Ni-61 [ng/g]
| |
| |Ni-62 [ng/g]
| |
| |Zr-90 [ng/g]
| |
| |Zr-91 [ng/g]
| |
| |Mo-95 [ng/g]
| |
| |Mo-97 [ng/g]
| |
| |Mo-98 [ng/g]
| |
| |Ag-107 [ng/g]
| |
| |Ag-109 [ng/g]
| |
| |Cs-133 [ng/g]
| |
| |Nd-143 [ng/g]
| |
| |Nd-145 [ng/g]
| |
| |Nd-146 [ng/g]
| |
| |U-234 [ng/g]
| |
| |U-235 [ng/g]
| |
| |U-236 [ng/g]
| |
| |U-238 [ng/g]
| |
| |-
| |
| |2PEN2101
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |8E+03 ± 2E+03
| |
| |8.9E+02 ± 4E+01
| |
| |1.93E+05 ± 5E+03
| |
| |4.2E+03 ± 2E+02
| |
| |1.90E+03 ± 1E+01
| |
| |9E+01 ± 1E+01
| |
| |2.4E+02 ± 1E+01
| |
| |2.43E+03 ± 2E+01
| |
| |6.0E+02 ± 5E+01
| |
| |7.6E+01 ± 8E+00
| |
| |5.6E+01 ± 1E+00
| |
| |1.26E+02 ± 3E+00
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |1.0E+01 ± 2E+00
| |
| |6E+00 ± 5E+00
| |
| |1.6E+01 ± 2E+00
| |
| |4E+00 ± 3E+00
| |
| |2.62E+02 ± 3E+00
| |
| |4.7E+01 ± 3E+00
| |
| |1.31E+04 ± 1E+02
| |
| |-
| |
| |2PEN2102
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |2.00E+05 ± 8E+03
| |
| |4.2E+03 ± 3E+02
| |
| |1.16E+03 ± 2E+01
| |
| |3E+01 ± 2E+01
| |
| |1.1E+02 ± 2E+01
| |
| |8.00E+03 ± 4E+01
| |
| |1.84E+03 ± 9E+01
| |
| |1.6E+02 ± 1E+01
| |
| |1.14E+02 ± 2E+00
| |
| |2.24E+02 ± 5E+00
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |3.3E+01 ± 3E+00
| |
| |1.4E+01 ± 8E+00
| |
| |2.6E+01 ± 3E+00
| |
| |1.2E+01 ± 5E+00
| |
| |7.46E+02 ± 5E+00
| |
| |1.32E+02 ± 5E+00
| |
| |3.86E+04 ± 2E+02
| |
| |-
| |
| |2WEL2101A
| |
| |<LOQ
| |
| |9.45E+03 ± 7E+01
| |
| |2.97E+04 ± 1E+02
| |
| |1.13E+05 ± 3E+03
| |
| |9.8E+04 ± 2E+03
| |
| |1.08E+04 ± 1E+02
| |
| |6.71E+08 ± 1E+06
| |
| |1.50E+07 ± 1E+05
| |
| |1.43E+05 ± 1E+03
| |
| |6.04E+03 ± 3E+01
| |
| |1.98E+04 ± 1E+02
| |
| |5.17E+04 ± 4E+02
| |
| |1.12E+04 ± 1E+02
| |
| |1.95E+05 ± 3E+03
| |
| |1.92E+05 ± 2E+03
| |
| |2.49E+05 ± 4E+03
| |
| |8.40E+02 ± 8E+00
| |
| |7.7E+03 ± 6E+02
| |
| |1.31E+04 ± 1E+02
| |
| |1.56E+02 ± 3E+00
| |
| |1.16E+02 ± 8E+00
| |
| |1.67E+02 ± 3E+00
| |
| |6E+01 ± 5E+01
| |
| |4.81E+03 ± 5E+01
| |
| |7.6E+02 ± 5E+01
| |
| |2.30E+05 ± 2E+03
| |
| |-
| |
| |2WEL2101C
| |
| |<LOQ
| |
| |<LOQ
| |
| |5.78E+04 ± 1E+02
| |
| |2.5E+05 ± 2E+04
| |
| |1.1E+05 ± 1E+04
| |
| |1.28E+04 ± 2E+02
| |
| |3.40E+08 ± 1E+06
| |
| |7.66E+06 ± 2E+04
| |
| |1.13E+05 ± 3E+03
| |
| |5.6E+03 ± 2E+02
| |
| |1.60E+04 ± 1E+02
| |
| |2.27E+04 ± 2E+02
| |
| |5.6E+03 ± 5E+02
| |
| |7.2E+04 ± 2E+03
| |
| |6.4E+04 ± 1E+03
| |
| |9.3E+04 ± 2E+03
| |
| |8.9E+02 ± 5E+01
| |
| |1.64E+04 ± 1E+02
| |
| |1.02E+04 ± 9E+02
| |
| |1.0E+02 ± 2E+01
| |
| |7E+01 ± 5E+01
| |
| |2.0E+02 ± 2E+01
| |
| |<LOQ
| |
| |2.15E+03 ± 3E+01
| |
| |3.6E+02 ± 3E+01
| |
| |1.04E+05 ± 1E+03
| |
| |-
| |
| |2WEL2102A
| |
| |<LOQ
| |
| |<LOQ
| |
| |1.18E+04 ± 1E+02
| |
| |4.7E+04 ± 2E+03
| |
| |1.21E+05 ± 1E+03
| |
| |1.33E+04 ± 1E+02
| |
| |8.45E+08 ± 2E+06
| |
| |1.88E+07 ± 1E+05
| |
| |6.87E+04 ± 2E+02
| |
| |2.80E+03 ± 2E+01
| |
| |9.16E+03 ± 1E+01
| |
| |<LOQ
| |
| |<LOQ
| |
| |2.4E+03 ± 2E+02
| |
| |1.5E+03 ± 1E+02
| |
| |3.8E+03 ± 2E+02
| |
| |2.08E+02 ± 5E+00
| |
| |1.99E+02 ± 1E+00
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |-
| |
| |2WEL2103A
| |
| |<LOQ
| |
| |<LOQ
| |
| |1.98E+04 ± 1E+02
| |
| |7.8E+04 ± 7E+03
| |
| |3.6E+04 ± 4E+03
| |
| |4.38E+03 ± 7E+01
| |
| |7.36E+08 ± 9E+06
| |
| |1.59E+07 ± 2E+05
| |
| |1.06E+04 ± 1E+02
| |
| |4.6E+02 ± 6E+01
| |
| |1.55E+03 ± 5E+01
| |
| |<LOQ
| |
| |<LOQ
| |
| |4.7E+02 ± 3E+01
| |
| |2.43E+02 ± 4E+00
| |
| |7.6E+02 ± 1E+01
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |2.4E+01 ± 8E+00
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |<LOQ
| |
| |-
| |
| |}
| |
| | |
| {| class="wikitable"
| |
| |+表(共通)-3 各元素の同位体比
| |
| !rowspan="2"|試料
| |
| !B
| |
| !Cr
| |
| !Fe
| |
| !colspan="2"|Ni
| |
| !Zr
| |
| !colspan="2"|Mo
| |
| !Ag
| |
| !colspan="2"|Nd
| |
| !U
| |
| |-
| |
| |(B-10/B-11)
| |
| |(Cr-53/Cr-52)
| |
| |(Fe-57/Fe-56)
| |
| |(Ni-61/Ni-60)
| |
| |(Ni-62/Ni-60)
| |
| |(Zr-91/Zr-90)
| |
| |(Mo-97/Mo-95)
| |
| |(Mo-98/Mo-95)
| |
| |(Ag-107/Ag-109)
| |
| |(Nd-143/Nd-146)
| |
| |(Nd-145/Nd-146)
| |
| |(U-235/U-238)
| |
| |-
| |
| |2PEN2101
| |
| |ー
| |
| |0.11±0.06
| |
| |0.022±0.002
| |
| |0.05±0.02
| |
| |0.13±0.01
| |
| |0.25±0.04
| |
| |0.7±0.2
| |
| |1.7±0.4
| |
| |ー
| |
| |0.6±0.3
| |
| |0.4±0.6
| |
| |0.0200±0.0006
| |
| |-
| |
| |2PEN2102
| |
| |ー
| |
| |ー
| |
| |0.021±0.004
| |
| |0.03±0.04
| |
| |0.09±0.04
| |
| |0.23±0.02
| |
| |0.7±0.1
| |
| |1.4±0.2
| |
| |ー
| |
| |1.3±0.4
| |
| |0.5±0.6
| |
| |0.0193±0.0003
| |
| |-
| |
| |2WEL2101A
| |
| |0.26±0.01
| |
| |0.111±0.004
| |
| |0.0223±0.0001
| |
| |0.0423±0.0005
| |
| |0.1383±0.0008
| |
| |0.216±0.004
| |
| |0.99±0.04
| |
| |1.27±0.06
| |
| |0.11±0.02
| |
| |0.94±0.05
| |
| |0.7±0.1
| |
| |0.0209±0.0006
| |
| |-
| |
| |2WEL2101C
| |
| |0.23±0.03
| |
| |0.11±0.02
| |
| |0.0225±0.0001
| |
| |0.049±0.004
| |
| |0.141±0.006
| |
| |0.25±0.05
| |
| |0.89±0.06
| |
| |1.3±0.1
| |
| |0.054±0.006
| |
| |0.5±0.2
| |
| |0.3±0.5
| |
| |0.0206±0.0008
| |
| |-
| |
| |2WEL2102A
| |
| |0.25±0.02
| |
| |0.110±0.002
| |
| |0.0223±0.0002
| |
| |0.0408±0.0005
| |
| |0.134±0.001
| |
| |ー
| |
| |0.64±0.1
| |
| |1.6±0.3
| |
| |1.04±0.05
| |
| |ー
| |
| |ー
| |
| |ー
| |
| |-
| |
| |2WEL2103A
| |
| |0.25±0.05
| |
| |0.12±0.03
| |
| |0.0216±0.0008
| |
| |0.04±0.01
| |
| |0.15±0.01
| |
| |ー
| |
| |0.51±0.07
| |
| |1.6±0.2
| |
| |ー
| |
| |ー
| |
| |ー
| |
| |ー
| |
| |-
| |
| |天然同位体比
| |
| |0.23
| |
| |0.116
| |
| |0.0235
| |
| |0.0442
| |
| |0.1432
| |
| |0.221
| |
| |0.62
| |
| |1.58
| |
| |1.06
| |
| |0.69
| |
| |0.48
| |
| |0.0072
| |
| |}
| |
| | |
| (2)定性分析結果
| |
| 全質量数スキャンにより得られた各質量数における計数率と正味計数率、及び核種の判定結果を、2PEN2102の結果と合わせて下表に示す。
| |
| 2PEN2101では、Fe、Al、Pb、Zn、Sb、U、Ca、Cu、Zr、Mn、Ni、Sn、Mo、V、Y、Gd、Pu、Np、Sr、Pr、Ag、Nd、Pd、Rh、Bi、As、Sm、Cdの計28元素が検出された。
| |
| | |
| {| class="wikitable"
| |
| |+表 ICP-MS定性分析での各質量数の計数率一覧表(2PEN2101、2PEN2102)(1/6)
| |
| !rowspan="2"|質量数(m/Z)
| |
| !colspan="3"|試料測定データ ①計数率 [cps]
| |
| !colspan="3"|ブランク液 測定データ計数率 [cps]
| |
| !colspan="3"|正味計数率 ①-②[cps]
| |
| !rowspan="2"|備考
| |
| |-
| |
| !操作ブランク
| |
| !2PEN2101
| |
| !2PEN2102
| |
| !ブランク液平均 ②μ
| |
| !ブランク液標準偏差σ
| |
| !検出限界(DL)μ+3σ
| |
| !操作ブランク
| |
| !2PEN2101
| |
| !2PEN2102
| |
| |-
| |
| | 6
| |
| | 7.78E+01
| |
| | 6.67E+01
| |
| | 6.67E+01
| |
| | 4.08E+01
| |
| | 1.28E+01
| |
| | 7.93E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 7
| |
| | 1.19E+03
| |
| | 1.38E+03
| |
| | 1.26E+03
| |
| | 5.19E+02
| |
| | 1.67E+02
| |
| | 1.02E+03
| |
| | 6.71E+02
| |
| | 8.60E+02
| |
| | 7.37E+02
| |
| | ※1 操作ブランクでガラス容器等から溶出する量は、経験上2倍程度の変動が確認されており、操作ブランクとの有意な差が認められない。
| |
| |-
| |
| | 8
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 4.45E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 9
| |
| | 2.22E+01
| |
| | 4.45E+01
| |
| | 4.45E+01
| |
| | 2.96E+01
| |
| | 1.70E+01
| |
| | 8.06E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 10
| |
| | 1.08E+04
| |
| | 1.28E+04
| |
| | 1.36E+04
| |
| | 7.90E+03
| |
| | 4.99E+02
| |
| | 9.39E+03
| |
| | 2.94E+03
| |
| | 4.86E+03
| |
| | 5.66E+03
| |
| | ※1 同上
| |
| |-
| |
| | 11
| |
| | 5.18E+04
| |
| | 5.68E+04
| |
| | 5.61E+04
| |
| | 3.61E+04
| |
| | 2.38E+03
| |
| | 4.32E+04
| |
| | 1.57E+04
| |
| | 2.07E+04
| |
| | 2.01E+04
| |
| | ※1 同上
| |
| |-
| |
| | 12
| |
| | 2.69E+07
| |
| | 3.36E+07
| |
| | 2.02E+07
| |
| | 4.03E+06
| |
| | 1.01E+05
| |
| | 4.33E+06
| |
| | 2.29E+07
| |
| | 2.96E+07
| |
| | 1.61E+07
| |
| | ※1 同上
| |
| |-
| |
| | 13
| |
| | 3.47E+05
| |
| | 4.30E+05
| |
| | 2.57E+05
| |
| | 5.01E+04
| |
| | 2.69E+03
| |
| | 5.81E+04
| |
| | 2.97E+05
| |
| | 3.79E+05
| |
| | 2.07E+05
| |
| | ※1 同上
| |
| |-
| |
| | 14
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | ※2 H, C, N, O, Ar等に由来する分子イオンによる妨害が大きい質量数のため、測定せず。
| |
| |-
| |
| | 15
| |
| | 1.72E+06
| |
| | 1.70E+06
| |
| | 1.75E+06
| |
| | 1.38E+06
| |
| | 4.17E+04
| |
| | 1.50E+06
| |
| | 3.46E+05
| |
| | 3.19E+05
| |
| | 3.70E+05
| |
| | ※3 H, C, N, O, Ar等に由来する分子イオンによる妨害が大きい質量数のため、同定せず。
| |
| |-
| |
| | 16
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | ※2 同上
| |
| |-
| |
| | 17
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | ※2 同上
| |
| |-
| |
| | 18
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | ※2 同上
| |
| |-
| |
| | 19
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | ※2 同上
| |
| |-
| |
| | 20
| |
| | 4.33E+06
| |
| | 4.47E+06
| |
| | 4.49E+06
| |
| | 4.85E+06
| |
| | 1.69E+05
| |
| | 5.36E+06
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 21
| |
| | 1.87E+05
| |
| | 1.90E+05
| |
| | 1.95E+05
| |
| | 2.03E+05
| |
| | 2.50E+03
| |
| | 2.11E+05
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 22
| |
| | 1.43E+03
| |
| | 1.92E+03
| |
| | 1.40E+03
| |
| | 1.11E+02
| |
| | 1.11E+01
| |
| | 1.45E+02
| |
| | 1.32E+03
| |
| | 1.81E+03
| |
| | 1.29E+03
| |
| | ※3 同上
| |
| |-
| |
| | 23
| |
| | 4.95E+06
| |
| | 5.80E+06
| |
| | 5.11E+06
| |
| | 1.22E+06
| |
| | 3.95E+04
| |
| | 1.34E+06
| |
| | 3.73E+06
| |
| | 4.58E+06
| |
| | 3.89E+06
| |
| | ※1 同上
| |
| |-
| |
| | 24
| |
| | 1.89E+06
| |
| | 2.39E+06
| |
| | 2.02E+06
| |
| | 1.08E+05
| |
| | 3.82E+03
| |
| | 1.19E+05
| |
| | 1.78E+06
| |
| | 2.28E+06
| |
| | 1.92E+06
| |
| | ※1 同上
| |
| |-
| |
| | 25
| |
| | 2.62E+05
| |
| | 3.28E+05
| |
| | 2.80E+05
| |
| | 1.48E+04
| |
| | 7.49E+02
| |
| | 1.70E+04
| |
| | 2.48E+05
| |
| | 3.13E+05
| |
| | 2.65E+05
| |
| | ※1 同上
| |
| |-
| |
| | 26
| |
| | 3.11E+05
| |
| | 3.96E+05
| |
| | 3.34E+05
| |
| | 1.80E+04
| |
| | 5.61E+02
| |
| | 1.96E+04
| |
| | 2.93E+05
| |
| | 3.78E+05
| |
| | 3.16E+05
| |
| | ※1 同上
| |
| |-
| |
| | 27
| |
| | 4.79E+05
| |
| | 1.09E+06
| |
| | 6.19E+05
| |
| | 1.53E+05
| |
| | 1.42E+04
| |
| | 1.96E+05
| |
| | 3.25E+05
| |
| | 9.34E+05
| |
| | 4.66E+05
| |
| | ※4 m/Z=27では、安定同位体として、Alのみが存在するため、Alと同定。
| |
| |-
| |
| | 28
| |
| | 5.43E+07
| |
| | 3.18E+06
| |
| | 4.71E+06
| |
| | 1.65E+06
| |
| | 1.43E+05
| |
| | 2.08E+06
| |
| | 5.26E+07
| |
| | 1.53E+06
| |
| | 3.06E+06
| |
| | ※1 同上
| |
| |-
| |
| | 29
| |
| | 3.79E+06
| |
| | 1.03E+06
| |
| | 1.07E+06
| |
| | 8.07E+05
| |
| | 1.15E+05
| |
| | 1.15E+06
| |
| | 2.98E+06
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 30
| |
| | 2.27E+07
| |
| | 2.07E+07
| |
| | 2.13E+07
| |
| | 1.98E+07
| |
| | 1.61E+06
| |
| | 2.46E+07
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 31
| |
| | 2.57E+05
| |
| | 2.51E+05
| |
| | 2.58E+05
| |
| | 2.31E+05
| |
| | 1.40E+04
| |
| | 2.73E+05
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 32
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | ※2 同上
| |
| |-
| |
| | 33
| |
| | 2.35E+07
| |
| | 2.43E+07
| |
| | 2.46E+07
| |
| | 2.75E+07
| |
| | 1.47E+06
| |
| | 3.19E+07
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 34
| |
| | 6.91E+05
| |
| | 7.54E+05
| |
| | 7.16E+05
| |
| | 9.63E+05
| |
| | 9.48E+04
| |
| | 1.25E+06
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 35
| |
| | 1.48E+05
| |
| | 1.48E+05
| |
| | 1.46E+05
| |
| | 1.50E+05
| |
| | 7.27E+03
| |
| | 1.72E+05
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 36
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | ※2 同上
| |
| |-
| |
| | 37
| |
| | 1.25E+07
| |
| | 1.28E+07
| |
| | 1.30E+07
| |
| | 1.41E+07
| |
| | 5.03E+05
| |
| | 1.56E+07
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 38
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | ※2 同上
| |
| |-
| |
| | 39
| |
| | 3.27E+06
| |
| | 3.62E+06
| |
| | 3.42E+06
| |
| | 2.86E+06
| |
| | 8.77E+04
| |
| | 3.13E+06
| |
| | 4.12E+05
| |
| | 7.56E+05
| |
| | 5.56E+05
| |
| | ※1 同上
| |
| |-
| |
| | 40
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | ※2 同上
| |
| |-
| |
| | 41
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | -
| |
| | ※2 同上
| |
| |-
| |
| | 42
| |
| | 7.32E+05
| |
| | 8.15E+05
| |
| | 7.74E+05
| |
| | 6.74E+05
| |
| | 2.26E+04
| |
| | 7.42E+05
| |
| | <DL
| |
| | 1.41E+05
| |
| | 9.99E+04
| |
| | ※5 m/Z=42では、安定同位体として、Caのみが存在するため、Caと同定。
| |
| |-
| |
| | 43
| |
| | 3.08E+04
| |
| | 4.23E+04
| |
| | 3.53E+04
| |
| | 1.87E+03
| |
| | 1.87E+02
| |
| | 2.43E+03
| |
| | 2.89E+04
| |
| | 4.04E+04
| |
| | 3.34E+04
| |
| | ※1 同上
| |
| |-
| |
| | 44
| |
| | 6.19E+05
| |
| | 7.59E+05
| |
| | 6.26E+05
| |
| | 9.30E+04
| |
| | 4.80E+03
| |
| | 1.07E+05
| |
| | 5.25E+05
| |
| | 6.66E+05
| |
| | 5.33E+05
| |
| | ※1 同上
| |
| |-
| |
| | 45
| |
| | 1.83E+05
| |
| | 2.44E+04
| |
| | 2.76E+04
| |
| | 1.83E+04
| |
| | 1.04E+03
| |
| | 2.14E+04
| |
| | 1.65E+05
| |
| | 6.11E+03
| |
| | 9.27E+03
| |
| | ※1 同上
| |
| |-
| |
| | 46
| |
| | 7.70E+04
| |
| | 2.73E+04
| |
| | 2.23E+04
| |
| | 1.35E+04
| |
| | 2.47E+03
| |
| | 2.09E+04
| |
| | 6.35E+04
| |
| | 1.37E+04
| |
| | 8.75E+03
| |
| | ※1 同上
| |
| |-
| |
| | 47
| |
| | 5.14E+04
| |
| | 7.05E+03
| |
| | 4.57E+03
| |
| | 8.52E+02
| |
| | 7.39E+01
| |
| | 1.07E+03
| |
| | 5.05E+04
| |
| | 6.20E+03
| |
| | 3.72E+03
| |
| | ※1 同上
| |
| |-
| |
| | 48
| |
| | 5.16E+05
| |
| | 1.32E+05
| |
| | 8.86E+04
| |
| | 1.93E+03
| |
| | 2.62E+02
| |
| | 2.72E+03
| |
| | 5.14E+05
| |
| | 1.30E+05
| |
| | 8.67E+04
| |
| | ※1 同上
| |
| |-
| |
| | 49
| |
| | 3.56E+04
| |
| | 4.49E+03
| |
| | 3.02E+03
| |
| | 3.37E+02
| |
| | 1.00E+02
| |
| | 6.38E+02
| |
| | 3.53E+04
| |
| | 4.15E+03
| |
| | 2.69E+03
| |
| | ※1 同上
| |
| |-
| |
| | 50
| |
| | 4.34E+04
| |
| | 1.41E+04
| |
| | 9.48E+03
| |
| | 1.27E+03
| |
| | 9.69E+01
| |
| | 1.56E+03
| |
| | 4.21E+04
| |
| | 1.28E+04
| |
| | 8.22E+03
| |
| | ※1 同上
| |
| |}
| |
| | |
| | |
| | |
| {| class="wikitable"
| |
| |+表 ICP-MS定性分析での各質量数の計数率一覧表(2PEN2101、2PEN2102)(2/6)
| |
| !rowspan="2"|質量数(m/Z)
| |
| !colspan="3"|試料測定データ ①計数率 [cps]
| |
| !colspan="3"|ブランク液 測定データ計数率 [cps]
| |
| !colspan="3"|正味計数率 ①-②[cps]
| |
| !rowspan="2"|備考
| |
| |-
| |
| !操作ブランク
| |
| !2PEN2101
| |
| !2PEN2102
| |
| !ブランク液平均 ②μ
| |
| !ブランク液標準偏差σ
| |
| !検出限界(DL)μ+3σ
| |
| !操作ブランク
| |
| !2PEN2101
| |
| !2PEN2102
| |
| |-
| |
| | 51
| |
| | 6.78E+02
| |
| | 2.82E+03
| |
| | 1.10E+03
| |
| | 2.19E+02
| |
| | 1.12E+02
| |
| | 5.54E+02
| |
| | 4.59E+02
| |
| | 2.60E+03
| |
| | 8.82E+02
| |
| |
| |
| |-
| |
| | 52
| |
| | 1.18E+05
| |
| | 2.00E+05
| |
| | 1.22E+05
| |
| | 1.24E+04
| |
| | 9.64E+02
| |
| | 1.53E+04
| |
| | 1.05E+05
| |
| | 1.88E+05
| |
| | 1.09E+05
| |
| | ※1 同上
| |
| |-
| |
| | 53
| |
| | 1.19E+04
| |
| | 2.04E+04
| |
| | 1.28E+04
| |
| | 4.08E+02
| |
| | 6.32E+01
| |
| | 5.97E+02
| |
| | 1.15E+04
| |
| | 2.00E+04
| |
| | 1.24E+04
| |
| |
| |
| |-
| |
| | 54
| |
| | 4.65E+05
| |
| | 6.08E+05
| |
| | 5.14E+05
| |
| | 3.28E+05
| |
| | 1.63E+04
| |
| | 3.77E+05
| |
| | 1.37E+05
| |
| | 2.79E+05
| |
| | 1.86E+05
| |
| | ※7 m/Z=54では、安定同位体として、FeとCrのみが存在するため、FeまたはCrと同定。
| |
| |-
| |
| | 55
| |
| | 2.38E+04
| |
| | 5.89E+04
| |
| | 3.66E+04
| |
| | 9.04E+03
| |
| | 3.30E+02
| |
| | 1.00E+04
| |
| | 1.48E+04
| |
| | 4.99E+04
| |
| | 2.76E+04
| |
| | ※8 m/Z=55では、安定同位体として、Mnのみが存在するため、Mnと同定。
| |
| |-
| |
| | 56
| |
| | 3.97E+06
| |
| | 6.35E+06
| |
| | 4.79E+06
| |
| | 3.25E+06
| |
| | 1.82E+05
| |
| | 3.79E+06
| |
| | 7.20E+05
| |
| | 3.10E+06
| |
| | 1.55E+06
| |
| | ※9 m/Z=56,57では、安定同位体として、Feのみが存在し、正味計数率の比が天然同位体比に近いため、Feと同定。
| |
| |-
| |
| | 57
| |
| | 7.94E+04
| |
| | 1.49E+05
| |
| | 1.04E+05
| |
| | 5.43E+04
| |
| | 4.77E+03
| |
| | 6.87E+04
| |
| | 2.50E+04
| |
| | 9.44E+04
| |
| | 4.98E+04
| |
| |
| |
| |-
| |
| | 58
| |
| | 3.99E+04
| |
| | 9.25E+04
| |
| | 6.33E+04
| |
| | 7.77E+03
| |
| | 8.61E+02
| |
| | 1.03E+04
| |
| | 3.21E+04
| |
| | 8.47E+04
| |
| | 5.56E+04
| |
| | ※10 m/Z=58では、安定同位体として、FeとNiのみが存在するため、FeまたはNiと同定。
| |
| |-
| |
| | 59
| |
| | 8.89E+02
| |
| | 2.83E+03
| |
| | 2.26E+03
| |
| | 3.08E+02
| |
| | 1.28E+01
| |
| | 3.46E+02
| |
| | 5.82E+02
| |
| | 2.53E+03
| |
| | 1.95E+03
| |
| | ※11 m/Z=59では、安定同位体と長半減期核種として、Co, Niが存在するため、CoまたはNiと同定。
| |
| |-
| |
| | 60
| |
| | 1.26E+04
| |
| | 3.12E+04
| |
| | 2.08E+04
| |
| | 2.85E+02
| |
| | 1.29E+02
| |
| | 6.72E+02
| |
| | 1.23E+04
| |
| | 3.10E+04
| |
| | 2.05E+04
| |
| | ※12 m/Z=60,61,62では、安定同位体として、Niのみが存在し、正味計数率の比が、Niの天然同位体組成に近いため、Niと同定。
| |
| |-
| |
| | 61
| |
| | 9.78E+02
| |
| | 1.91E+03
| |
| | 1.75E+03
| |
| | 4.82E+01
| |
| | 2.57E+01
| |
| | 1.25E+02
| |
| | 9.30E+02
| |
| | 1.86E+03
| |
| | 1.70E+03
| |
| |
| |
| |-
| |
| | 62
| |
| | 1.93E+03
| |
| | 4.40E+03
| |
| | 3.07E+03
| |
| | 3.52E+02
| |
| | 6.41E+00
| |
| | 3.71E+02
| |
| | 1.58E+03
| |
| | 4.05E+03
| |
| | 2.72E+03
| |
| |
| |
| |-
| |
| | 63
| |
| | 1.95E+04
| |
| | 8.99E+04
| |
| | 2.04E+04
| |
| | 5.58E+03
| |
| | 5.87E+01
| |
| | 5.76E+03
| |
| | 1.39E+04
| |
| | 8.43E+04
| |
| | 1.49E+04
| |
| | ※13 m/Z=63,65では、安定同位体として、Cuのみが存在し、正味計数率の比が、Cuの天然同位体組成に近いため、Cuと同定。
| |
| |-
| |
| | 64
| |
| | 6.05E+04
| |
| | 4.13E+05
| |
| | 1.21E+05
| |
| | 6.53E+03
| |
| | 1.47E+03
| |
| | 1.09E+04
| |
| | 5.40E+04
| |
| | 4.06E+05
| |
| | 1.14E+05
| |
| | ※14 m/Z=64,66,67,68,70での正味計数率の比が、Znの天然同位体組成に近いため、Znと同定。
| |
| |-
| |
| | 65
| |
| | 9.49E+03
| |
| | 4.37E+04
| |
| | 9.37E+03
| |
| | 2.23E+03
| |
| | 1.11E+02
| |
| | 2.56E+03
| |
| | 7.26E+03
| |
| | 4.14E+04
| |
| | 7.14E+03
| |
| | ※13 同上
| |
| |-
| |
| | 66
| |
| | 3.58E+04
| |
| | 2.44E+05
| |
| | 7.25E+04
| |
| | 3.75E+03
| |
| | 9.41E+02
| |
| | 6.58E+03
| |
| | 3.21E+04
| |
| | 2.40E+05
| |
| | 6.87E+04
| |
| | ※14 同上
| |
| |-
| |
| | 67
| |
| | 5.61E+03
| |
| | 3.78E+04
| |
| | 1.08E+04
| |
| | 6.15E+02
| |
| | 1.71E+02
| |
| | 1.13E+03
| |
| | 5.00E+03
| |
| | 3.72E+04
| |
| | 1.01E+04
| |
| | ※14 同上
| |
| |-
| |
| | 68
| |
| | 2.60E+04
| |
| | 1.72E+05
| |
| | 5.34E+04
| |
| | 3.62E+03
| |
| | 7.17E+02
| |
| | 5.77E+03
| |
| | 2.24E+04
| |
| | 1.68E+05
| |
| | 4.98E+04
| |
| | ※14 同上
| |
| |-
| |
| | 69
| |
| | 6.56E+03
| |
| | 8.23E+03
| |
| | 5.34E+03
| |
| | 4.56E+02
| |
| | 9.69E+01
| |
| | 7.46E+02
| |
| | 6.10E+03
| |
| | 7.77E+03
| |
| | 4.88E+03
| |
| | ※1 同上
| |
| |-
| |
| | 70
| |
| | 3.15E+03
| |
| | 7.73E+03
| |
| | 3.32E+03
| |
| | 1.74E+03
| |
| | 1.89E+02
| |
| | 2.31E+03
| |
| | 1.40E+03
| |
| | 5.99E+03
| |
| | 1.58E+03
| |
| | ※14 同上
| |
| |-
| |
| | 71
| |
| | 1.89E+02
| |
| | 2.78E+02
| |
| | 2.22E+02
| |
| | 1.63E+02
| |
| | 5.13E+01
| |
| | 3.17E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 72
| |
| | 7.45E+02
| |
| | 6.45E+02
| |
| | 6.22E+02
| |
| | 5.59E+02
| |
| | 1.22E+02
| |
| | 9.25E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 73
| |
| | 1.22E+02
| |
| | 8.89E+01
| |
| | 1.22E+02
| |
| | 8.15E+01
| |
| | 1.70E+01
| |
| | 1.32E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 74
| |
| | 1.22E+02
| |
| | 5.56E+01
| |
| | 4.45E+01
| |
| | 3.33E+01
| |
| | 1.93E+01
| |
| | 9.11E+01
| |
| | 8.89E+01
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 75
| |
| | 1.22E+02
| |
| | 2.67E+02
| |
| | 1.00E+02
| |
| | 5.93E+01
| |
| | 3.57E+01
| |
| | 1.66E+02
| |
| | <DL
| |
| | 207
| |
| | <DL
| |
| | ※15 m/Z=75では、安定同位体として、Asのみが存在するため、Asと同定。
| |
| |-
| |
| | 76
| |
| | 6.49E+04
| |
| | 6.40E+04
| |
| | 6.55E+04
| |
| | 6.36E+04
| |
| | 4.17E+03
| |
| | 7.61E+04
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 77
| |
| | 4.45E+01
| |
| | 1.00E+02
| |
| | 7.78E+01
| |
| | 5.93E+01
| |
| | 1.70E+01
| |
| | 1.10E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 78
| |
| | 1.29E+04
| |
| | 1.25E+04
| |
| | 1.18E+04
| |
| | 1.22E+04
| |
| | 8.00E+02
| |
| | 1.46E+04
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 79
| |
| | 1.71E+03
| |
| | 1.87E+03
| |
| | 1.95E+03
| |
| | 1.79E+03
| |
| | 3.00E+02
| |
| | 2.69E+03
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 80
| |
| | 1.05E+07
| |
| | 1.05E+07
| |
| | 1.05E+07
| |
| | 1.02E+07
| |
| | 4.70E+05
| |
| | 1.16E+07
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 81
| |
| | 7.68E+03
| |
| | 7.56E+03
| |
| | 7.89E+03
| |
| | 6.89E+03
| |
| | 5.49E+02
| |
| | 8.54E+03
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |- | |
| | 82
| |
| | 2.78E+02
| |
| | 2.22E+02
| |
| | 3.33E+02
| |
| | 2.19E+02
| |
| | 4.49E+01
| |
| | 3.53E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 83
| |
| | 2.11E+02
| |
| | 3.11E+02
| |
| | 2.00E+02
| |
| | 1.78E+02
| |
| | 1.13E+02
| |
| | 5.16E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 84
| |
| | 1.85E+03
| |
| | 2.10E+03
| |
| | 2.07E+03
| |
| | 1.22E+03
| |
| | 2.12E+02
| |
| | 1.86E+03
| |
| | <DL
| |
| | 8.78E+02
| |
| | 8.45E+02
| |
| | ※16 m/Z=84では、安定同位体として、KrとSrのみが存在し、Krが溶液化後の試料中に残存する可能性は低いため、Srと同定。
| |
| |-
| |
| | 85
| |
| | 2.50E+03
| |
| | 3.79E+03
| |
| | 2.52E+03
| |
| | 7.08E+02
| |
| | 1.34E+02
| |
| | 1.11E+03
| |
| | 1.79E+03
| |
| | 3.08E+03
| |
| | 1.82E+03
| |
| | ※1 同上
| |
| |-
| |
| | 86
| |
| | 1.14E+04
| |
| | 1.64E+04
| |
| | 1.39E+04
| |
| | 5.74E+02
| |
| | 2.00E+02
| |
| | 1.17E+03
| |
| | 1.09E+04
| |
| | 1.58E+04
| |
| | 1.33E+04
| |
| | ※1 同上
| |
| |-
| |
| | 87
| |
| | 9.25E+03
| |
| | 1.29E+04
| |
| | 1.02E+04
| |
| | 3.89E+02
| |
| | 2.94E+01
| |
| | 4.77E+02
| |
| | 8.86E+03
| |
| | 1.25E+04
| |
| | 9.83E+03
| |
| | ※1 同上
| |
| |-
| |
| | 88
| |
| | 1.04E+05
| |
| | 1.34E+05
| |
| | 1.11E+05
| |
| | 7.78E+02
| |
| | 2.67E+02
| |
| | 1.58E+03
| |
| | 1.04E+05
| |
| | 1.34E+05
| |
| | 1.10E+05
| |
| | ※1 同上
| |
| |-
| |
| | 89
| |
| | 4.22E+02
| |
| | 1.39E+03
| |
| | 7.56E+02
| |
| | 4.82E+01
| |
| | 3.21E+01
| |
| | 1.44E+02
| |
| | 3.74E+02
| |
| | 1.34E+03
| |
| | 7.08E+02
| |
| | ※17 m/Z=89では、安定同位体として、Yのみが存在するため、Yと同定。
| |
| |}
| |
| | |
| | |
| | |
| {| class="wikitable"
| |
| |+表 ICP-MS定性分析での各質量数の計数率一覧表(2PEN2101、2PEN2102)(3/6)
| |
| !rowspan="2"|質量数(m/Z)
| |
| !colspan="3"|試料測定データ ①計数率 [cps]
| |
| !colspan="3"|ブランク液 測定データ計数率 [cps]
| |
| !colspan="3"|正味計数率 ①-②[cps]
| |
| !rowspan="2"|備考
| |
| |-
| |
| !操作ブランク
| |
| !2PEN2101
| |
| !2PEN2102
| |
| !ブランク液平均 ②μ
| |
| !ブランク液標準偏差σ
| |
| !検出限界(DL)μ+3σ
| |
| !操作ブランク
| |
| !2PEN2101
| |
| !2PEN2102
| |
| |-
| |
| | 90
| |
| | 5.77E+03
| |
| | 5.75E+04
| |
| | 1.13E+05
| |
| | 3.82E+02
| |
| | 5.25E+01
| |
| | 5.39E+02
| |
| | 5.39E+03
| |
| | 5.71E+04
| |
| | 1.13E+05
| |
| |
| |
| |-
| |
| | 91
| |
| | 1.78E+03
| |
| | 1.26E+04
| |
| | 2.50E+04
| |
| | 5.93E+01
| |
| | 2.31E+01
| |
| | 1.29E+02
| |
| | 1.72E+03
| |
| | 1.25E+04
| |
| | 2.49E+04
| |
| |
| |
| |-
| |
| | 92
| |
| | 2.90E+03
| |
| | 2.12E+04
| |
| | 4.08E+04
| |
| | 1.85E+02
| |
| | 2.80E+01
| |
| | 2.69E+02
| |
| | 2.72E+03
| |
| | 2.11E+04
| |
| | 4.07E+04
| |
| |
| |
| |-
| |
| | 93
| |
| | 1.28E+03
| |
| | 1.00E+03
| |
| | 1.21E+03
| |
| | 2.59E+01
| |
| | 2.80E+01
| |
| | 1.10E+02
| |
| | 1.25E+03
| |
| | 9.74E+02
| |
| | 1.19E+03
| |
| | ※1 同上
| |
| |-
| |
| | 94
| |
| | 3.41E+03
| |
| | 2.14E+04
| |
| | 4.25E+04
| |
| | 2.26E+02
| |
| | 5.01E+01
| |
| | 3.76E+02
| |
| | 3.19E+03
| |
| | 2.12E+04
| |
| | 4.22E+04
| |
| | ※19 同上
| |
| |-
| |
| | 95
| |
| | 5.45E+02
| |
| | 2.33E+03
| |
| | 2.20E+03
| |
| | 1.74E+02
| |
| | 1.48E+02
| |
| | 6.18E+02
| |
| | <DL
| |
| | 2.16E+03
| |
| | 2.03E+03
| |
| | ※20 m/Z=95,97では、安定同位体として、Moのみが存在するため、Moと同定。
| |
| |-
| |
| | 96
| |
| | 1.86E+03
| |
| | 5.89E+03
| |
| | 9.23E+03
| |
| | 1.33E+02
| |
| | 3.85E+01
| |
| | 2.49E+02
| |
| | 1.72E+03
| |
| | 5.76E+03
| |
| | 9.09E+03
| |
| | ※19 同上
| |
| |-
| |
| | 97
| |
| | 3.22E+02
| |
| | 1.51E+03
| |
| | 1.72E+03
| |
| | 1.48E+02
| |
| | 1.33E+02
| |
| | 5.46E+02
| |
| | <DL
| |
| | 1.36E+03
| |
| | 1.57E+03
| |
| | ※20 同上
| |
| |-
| |
| | 98
| |
| | 8.89E+02
| |
| | 2.97E+03
| |
| | 3.13E+03
| |
| | 2.45E+02
| |
| | 1.73E+02
| |
| | 7.62E+02
| |
| | 6.45E+02
| |
| | 2.72E+03
| |
| | 2.89E+03
| |
| | ※21 m/Z=98,100では、安定同位体として、MoとRuのみが存在し、m/Z=101でRuの検出がないため、Moと同定。
| |
| |-
| |
| | 99
| |
| | 1.11E+02
| |
| | 2.56E+02
| |
| | 3.33E+02
| |
| | 7.78E+01
| |
| | 7.29E+01
| |
| | 2.96E+02
| |
| | <DL
| |
| | <DL
| |
| | 2.56E+02
| |
| | ※22 m/Z=99では、安定同位体や長半減期核種として、TcとRuのみが存在し、m/Z=101でRuの検出がないため、Tcと同定。
| |
| |-
| |
| | 100
| |
| | 4.00E+02
| |
| | 1.83E+03
| |
| | 2.00E+03
| |
| | 1.82E+02
| |
| | 1.24E+02
| |
| | 5.53E+02
| |
| | <DL
| |
| | 1.65E+03
| |
| | 1.82E+03
| |
| | ※21 同上
| |
| |-
| |
| | 101
| |
| | 1.17E+03
| |
| | 1.35E+03
| |
| | 1.21E+03
| |
| | 8.19E+02
| |
| | 4.85E+02
| |
| | 2.27E+03
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 102
| |
| | 3.45E+02
| |
| | 6.56E+02
| |
| | 8.23E+02
| |
| | 3.63E+02
| |
| | 1.39E+02
| |
| | 7.80E+02
| |
| | <DL
| |
| | <DL
| |
| | 4.59E+02
| |
| |
| |
| |-
| |
| | 103
| |
| | 1.11E+02
| |
| | 3.11E+02
| |
| | 4.89E+02
| |
| | 1.07E+02
| |
| | 8.19E+01
| |
| | 3.53E+02
| |
| | <DL
| |
| | <DL
| |
| | 3.82E+02
| |
| | ※23 m/Z=103では、安定同位体として、Rhのみが存在するため、Rhと同定。
| |
| |-
| |
| | 104
| |
| | 5.56E+01
| |
| | 3.89E+02
| |
| | 2.33E+02
| |
| | 4.45E+01
| |
| | 1.11E+01
| |
| | 7.78E+01
| |
| | <DL
| |
| | 3.45E+02
| |
| | 1.89E+02
| |
| | ※24 m/Z=104では、安定同位体としてRuとPdのみが存在し、m/Z=101でRuの検出がないため、Pdと同定。
| |
| |-
| |
| | 105
| |
| | 1.56E+02
| |
| | 1.89E+02
| |
| | 1.67E+02
| |
| | 3.70E+01
| |
| | 1.70E+01
| |
| | 8.80E+01
| |
| | 1.19E+02
| |
| | 1.52E+02
| |
| | 1.30E+02
| |
| | ※1 同上
| |
| |-
| |
| | 106
| |
| | 1.67E+02
| |
| | 6.78E+02
| |
| | 1.22E+03
| |
| | 7.04E+01
| |
| | 4.49E+01
| |
| | 2.05E+02
| |
| | <DL
| |
| | 6.08E+02
| |
| | 1.15E+03
| |
| | ※25 m/Z=106, 108, 110では、安定同位体としてPdとCdのみが存在するため、PdまたはCdと同定。
| |
| |-
| |
| | 107
| |
| | 3.45E+02
| |
| | 6.45E+02
| |
| | 7.67E+02
| |
| | 1.22E+02
| |
| | 2.94E+01
| |
| | 2.11E+02
| |
| | 2.22E+02
| |
| | 5.22E+02
| |
| | 6.45E+02
| |
| | ※26 m/Z=107では、安定同位体や長半減期核種として、PdとAgのみが存在し、m/Z=105でPdの検出が認められないため、Agと同定。
| |
| |-
| |
| | 108
| |
| | 7.78E+01
| |
| | 4.00E+02
| |
| | 3.56E+02
| |
| | 5.93E+01
| |
| | 1.28E+01
| |
| | 9.78E+01
| |
| | <DL
| |
| | 3.41E+02
| |
| | 2.96E+02
| |
| | ※25 同上
| |
| |-
| |
| | 109
| |
| | 3.45E+02
| |
| | 4.45E+02
| |
| | 2.56E+02
| |
| | 1.26E+02
| |
| | 3.90E+01
| |
| | 2.43E+02
| |
| | 2.19E+02
| |
| | 3.19E+02
| |
| | 1.30E+02
| |
| | ※1 同上
| |
| |-
| |
| | 110
| |
| | 1.44E+02
| |
| | 3.33E+02
| |
| | 5.34E+02
| |
| | 4.45E+01
| |
| | 2.94E+01
| |
| | 1.33E+02
| |
| | 1.00E+02
| |
| | 2.89E+02
| |
| | 4.89E+02
| |
| | ※25 同上
| |
| |-
| |
| | 111
| |
| | 4.45E+01
| |
| | 1.33E+02
| |
| | 1.56E+02
| |
| | 7.41E+00
| |
| | 6.42E+00
| |
| | 2.67E+01
| |
| | 3.70E+01
| |
| | 1.26E+02
| |
| | 1.48E+02
| |
| | ※27 m/Z=111では、安定同位体として、Cdのみが存在するため、Cdと同定。
| |
| |-
| |
| | 112
| |
| | 1.22E+02
| |
| | 2.89E+02
| |
| | 2.00E+02
| |
| | 8.15E+01
| |
| | 3.90E+01
| |
| | 1.99E+02
| |
| | <DL
| |
| | 2.07E+02
| |
| | 1.19E+02
| |
| | ※28 m/Z=112,116では、安定同位体として、CdとSnのみが存在するため、CdまたはSnと同定。
| |
| |-
| |
| | 113
| |
| | 6.67E+01
| |
| | 5.56E+01
| |
| | 7.78E+01
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 5.56E+01
| |
| | 4.45E+01
| |
| | 3.33E+01
| |
| | 5.56E+01
| |
| |
| |
| |-
| |
| | 114
| |
| | 1.44E+02
| |
| | 1.78E+02
| |
| | 1.33E+02
| |
| | 8.15E+01
| |
| | 1.70E+01
| |
| | 1.32E+02
| |
| | 6.30E+01
| |
| | 9.63E+01
| |
| | 5.19E+01
| |
| | ※1 同上
| |
| |-
| |
| | 115
| |
| | 5.56E+01
| |
| | 2.33E+02
| |
| | 1.00E+02
| |
| | 4.08E+01
| |
| | 1.28E+01
| |
| | 7.93E+01
| |
| | <DL
| |
| | 1.93E+02
| |
| | 5.93E+01
| |
| | ※29 m/Z=115では、安定同位体として、InとSnのみが存在するため、InまたはSnと同定。
| |
| |-
| |
| | 116
| |
| | 1.32E+03
| |
| | 2.57E+03
| |
| | 1.93E+03
| |
| | 8.56E+02
| |
| | 6.76E+01
| |
| | 1.06E+03
| |
| | 4.67E+02
| |
| | 1.71E+03
| |
| | 1.08E+03
| |
| | ※28 同上
| |
| |-
| |
| | 117
| |
| | 5.78E+02
| |
| | 1.28E+03
| |
| | 8.56E+02
| |
| | 5.34E+02
| |
| | 1.07E+02
| |
| | 8.55E+02
| |
| | <DL
| |
| | 7.45E+02
| |
| | 3.22E+02
| |
| | ※30 m/Z=117-119では、安定同位体として、Snのみが存在するため、Snと同定。
| |
| |-
| |
| | 118
| |
| | 2.08E+03
| |
| | 4.00E+03
| |
| | 3.28E+03
| |
| | 1.62E+03
| |
| | 6.76E+01
| |
| | 1.83E+03
| |
| | 4.56E+02
| |
| | 2.38E+03
| |
| | 1.66E+03
| |
| | ※30 同上
| |
| |-
| |
| | 119
| |
| | 6.11E+02
| |
| | 5.43E+03
| |
| | 7.67E+03
| |
| | 5.74E+02
| |
| | 5.01E+01
| |
| | 7.25E+02
| |
| | <DL
| |
| | 4.85E+03
| |
| | 7.10E+03
| |
| | ※30 同上
| |
| |-
| |
| | 120
| |
| | 2.53E+03
| |
| | 5.50E+03
| |
| | 4.22E+03
| |
| | 2.18E+03
| |
| | 3.39E+01
| |
| | 2.28E+03
| |
| | 3.52E+02
| |
| | 3.32E+03
| |
| | 2.04E+03
| |
| | ※31 m/Z=120,122では、安定同位体として、SnとTeのみが存在し、他m/ZでTeの検出が認められないため、Snと同定。
| |
| |-
| |
| |}
| |
| | |
| | |
| | |
| {| class="wikitable"
| |
| |+表 ICP-MS定性分析での各質量数の計数率一覧表(2PEN2101、2PEN2102)(4/6)
| |
| !rowspan="2"|質量数(m/Z)
| |
| !colspan="3"|試料測定データ ①計数率 [cps]
| |
| !colspan="3"|ブランク液 測定データ計数率 [cps]
| |
| !colspan="3"|正味計数率 ①-②[cps]
| |
| !rowspan="2"|備考
| |
| |-
| |
| !操作ブランク
| |
| !2PEN2101
| |
| !2PEN2102
| |
| !ブランク液平均 ②μ
| |
| !ブランク液標準偏差σ
| |
| !検出限界(DL)μ+3σ
| |
| !操作ブランク
| |
| !2PEN2101
| |
| !2PEN2102
| |
| |-
| |
| | 121
| |
| | 1.62E+03
| |
| | 2.03E+05
| |
| | 7.66E+03
| |
| | 1.11E+02
| |
| | 1.11E+01
| |
| | 1.44E+02
| |
| | 1.51E+03
| |
| | 2.03E+05
| |
| | 7.55E+03
| |
| |
| |
| |-
| |
| | 122
| |
| | 4.22E+02
| |
| | 7.67E+02
| |
| | 6.11E+02
| |
| | 3.04E+02
| |
| | 7.40E+01
| |
| | 5.26E+02
| |
| | <DL
| |
| | 4.63E+02
| |
| | 3.08E+02
| |
| | ※31 同上
| |
| |-
| |
| | 123
| |
| | 1.20E+03
| |
| | 1.57E+05
| |
| | 5.37E+03
| |
| | 8.52E+01
| |
| | 1.70E+01
| |
| | 1.36E+02
| |
| | 1.12E+03
| |
| | 1.57E+05
| |
| | 5.28E+03
| |
| |
| |
| |-
| |
| | 124
| |
| | 5.45E+02
| |
| | 1.10E+03
| |
| | 7.22E+02
| |
| | 4.59E+02
| |
| | 2.31E+01
| |
| | 5.29E+02
| |
| | 8.52E+01
| |
| | 6.41E+02
| |
| | 2.63E+02
| |
| | ※34 m/Z=124では、安定同位体として、SnとTeとXeのみが存在し、Xeが溶液化後の試料中に残存する可能性は低いため、他m/ZでTeの検出が認められないため、Snと同定。
| |
| |-
| |
| | 125
| |
| | 1.11E+01
| |
| | 0.00E+00
| |
| | 0.00E+00
| |
| | 7.41E+00
| |
| | 6.42E+00
| |
| | 2.67E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 126
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 3.34E+01
| |
| | 1.85E+01
| |
| | 1.70E+01
| |
| | 6.95E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 127
| |
| | 4.54E+03
| |
| | 4.51E+03
| |
| | 4.79E+03
| |
| | 1.57E+03
| |
| | 1.87E+02
| |
| | 2.13E+03
| |
| | 2.97E+03
| |
| | 2.95E+03
| |
| | 3.22E+03
| |
| | ※1 同上
| |
| |-
| |
| | 128
| |
| | 2.00E+02
| |
| | 1.89E+02
| |
| | 2.22E+02
| |
| | 1.56E+02
| |
| | 5.56E+01
| |
| | 3.22E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 129
| |
| | 2.60E+03
| |
| | 1.93E+03
| |
| | 2.23E+03
| |
| | 2.28E+03
| |
| | 2.57E+02
| |
| | 3.05E+03
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 130
| |
| | 4.89E+02
| |
| | 6.56E+02
| |
| | 6.00E+02
| |
| | 3.41E+02
| |
| | 3.40E+01
| |
| | 4.43E+02
| |
| | 1.48E+02
| |
| | 3.15E+02
| |
| | 2.59E+02
| |
| | ※35 m/Z=130では、安定同位体として、TeとXeとBaのみが存在し、Xeが溶液化後の試料中に残存する可能性は低いため、TeまたはBaと同定。
| |
| |-
| |
| | 131
| |
| | 1.96E+03
| |
| | 1.72E+03
| |
| | 1.80E+03
| |
| | 1.83E+03
| |
| | 1.09E+02
| |
| | 2.16E+03
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 132
| |
| | 2.83E+03
| |
| | 2.46E+03
| |
| | 2.52E+03
| |
| | 2.44E+03
| |
| | 1.99E+02
| |
| | 3.04E+03
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 133
| |
| | 3.36E+03
| |
| | 2.92E+03
| |
| | 2.88E+03
| |
| | 2.55E+03
| |
| | 1.41E+02
| |
| | 2.98E+03
| |
| | 8.04E+02
| |
| | <DL
| |
| | <DL
| |
| | ※1 同上
| |
| |-
| |
| | 134
| |
| | 4.36E+03
| |
| | 5.04E+03
| |
| | 3.43E+03
| |
| | 1.06E+03
| |
| | 8.98E+01
| |
| | 1.33E+03
| |
| | 3.30E+03
| |
| | 3.98E+03
| |
| | 2.38E+03
| |
| | ※1 同上
| |
| |-
| |
| | 135
| |
| | 1.01E+04
| |
| | 1.24E+04
| |
| | 7.98E+03
| |
| | 7.63E+02
| |
| | 1.17E+02
| |
| | 1.11E+03
| |
| | 9.38E+03
| |
| | 1.16E+04
| |
| | 7.22E+03
| |
| | ※1 同上
| |
| |-
| |
| | 136
| |
| | 1.20E+04
| |
| | 1.50E+04
| |
| | 1.01E+04
| |
| | 1.20E+03
| |
| | 2.13E+02
| |
| | 1.84E+03
| |
| | 1.08E+04
| |
| | 1.38E+04
| |
| | 8.88E+03
| |
| | ※1 同上
| |
| |-
| |
| | 137
| |
| | 1.68E+04
| |
| | 2.21E+04
| |
| | 1.43E+04
| |
| | 1.34E+03
| |
| | 2.04E+02
| |
| | 1.96E+03
| |
| | 1.55E+04
| |
| | 2.07E+04
| |
| | 1.29E+04
| |
| | ※1 同上
| |
| |-
| |
| | 138
| |
| | 1.04E+05
| |
| | 1.27E+05
| |
| | 8.56E+04
| |
| | 3.40E+03
| |
| | 3.23E+02
| |
| | 4.37E+03
| |
| | 1.00E+05
| |
| | 1.24E+05
| |
| | 8.22E+04
| |
| | ※1 同上
| |
| |-
| |
| | 139
| |
| | 2.98E+04
| |
| | 1.93E+03
| |
| | 1.55E+03
| |
| | 7.41E+01
| |
| | 5.70E+01
| |
| | 2.45E+02
| |
| | 2.98E+04
| |
| | 1.86E+03
| |
| | 1.47E+03
| |
| | ※1 同上
| |
| |-
| |
| | 140
| |
| | 2.78E+04
| |
| | 1.32E+04
| |
| | 1.07E+04
| |
| | 3.08E+02
| |
| | 8.49E+01
| |
| | 5.62E+02
| |
| | 2.75E+04
| |
| | 1.29E+04
| |
| | 1.04E+04
| |
| | ※1 同上
| |
| |-
| |
| | 141
| |
| | 1.45E+02
| |
| | 6.89E+02
| |
| | 8.00E+02
| |
| | 1.85E+01
| |
| | 6.42E+00
| |
| | 3.78E+01
| |
| | 1.26E+02
| |
| | 6.71E+02
| |
| | 7.82E+02
| |
| | ※36 m/Z=141では、安定同位体として、Prのみが存在するため、Prと同定。
| |
| |-
| |
| | 142
| |
| | 3.72E+03
| |
| | 2.03E+03
| |
| | 1.73E+03
| |
| | 9.66E+02
| |
| | 1.62E+03
| |
| | 5.81E+03
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 143
| |
| | 4.45E+01
| |
| | 3.00E+02
| |
| | 5.56E+02
| |
| | 0.00E+00
| |
| | 0.00E+00
| |
| | 0.00E+00
| |
| | 4.45E+01
| |
| | 3.00E+02
| |
| | 5.56E+02
| |
| | ※37 m/Z=143, 145, 146では、安定同位体として、Ndのみが存在するため、Ndと同定。
| |
| |-
| |
| | 144
| |
| | 1.22E+02
| |
| | 4.78E+02
| |
| | 7.56E+02
| |
| | 7.41E+00
| |
| | 1.28E+01
| |
| | 4.59E+01
| |
| | 1.15E+02
| |
| | 4.71E+02
| |
| | 7.48E+02
| |
| |
| |
| |-
| |
| | 145
| |
| | 6.67E+01
| |
| | 2.89E+02
| |
| | 3.45E+02
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 4.45E+01
| |
| | 5.56E+01
| |
| | 2.78E+02
| |
| | 3.33E+02
| |
| | ※37 同上
| |
| |-
| |
| | 146
| |
| | 1.56E+02
| |
| | 4.34E+02
| |
| | 4.22E+02
| |
| | 3.70E+01
| |
| | 2.80E+01
| |
| | 1.21E+02
| |
| | 1.19E+02
| |
| | 3.96E+02
| |
| | 3.85E+02
| |
| | ※37 同上
| |
| |-
| |
| | 147
| |
| | 4.45E+01
| |
| | 1.78E+02
| |
| | 1.67E+02
| |
| | 1.48E+01
| |
| | 6.42E+00
| |
| | 3.41E+01
| |
| | 2.96E+01
| |
| | 1.63E+02
| |
| | 1.52E+02
| |
| | ※39 m/Z=147では、安定同位体として、Smのみが存在するため、Smと同定。
| |
| |-
| |
| | 148
| |
| | 8.89E+01
| |
| | 2.89E+02
| |
| | 2.78E+02
| |
| | 1.48E+01
| |
| | 6.42E+00
| |
| | 3.41E+01
| |
| | 7.41E+01
| |
| | 2.74E+02
| |
| | 2.63E+02
| |
| | ※38 同上
| |
| |-
| |
| | 149
| |
| | 6.67E+01
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 2.96E+01
| |
| | 2.80E+01
| |
| | 1.14E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 150
| |
| | 1.11E+02
| |
| | 1.45E+02
| |
| | 2.78E+02
| |
| | 1.11E+01
| |
| | 1.93E+01
| |
| | 6.89E+01
| |
| | 1.00E+02
| |
| | 1.33E+02
| |
| | 2.67E+02
| |
| | ※38 同上
| |
| |-
| |
| | 151
| |
| | 6.67E+01
| |
| | 7.78E+01
| |
| | 0.00E+00
| |
| | 7.41E+00
| |
| | 6.42E+00
| |
| | 2.67E+01
| |
| | 5.93E+01
| |
| | 7.04E+01
| |
| | <DL
| |
| | ※1 同上
| |
| |-
| |
| | 152
| |
| | 1.78E+02
| |
| | 1.22E+02
| |
| | 1.67E+02
| |
| | 1.85E+01
| |
| | 1.70E+01
| |
| | 6.95E+01
| |
| | 1.59E+02
| |
| | 1.04E+02
| |
| | 1.48E+02
| |
| |
| |
| |-
| |
| | 153
| |
| | 1.11E+02
| |
| | 8.89E+01
| |
| | 1.89E+02
| |
| | 7.41E+00
| |
| | 6.42E+00
| |
| | 2.67E+01
| |
| | 1.04E+02
| |
| | 8.15E+01
| |
| | 1.82E+02
| |
| | ※1 同上
| |
| |-
| |
| | 154
| |
| | 2.33E+02
| |
| | 2.11E+02
| |
| | 2.56E+02
| |
| | 3.70E+01
| |
| | 6.42E+00
| |
| | 5.63E+01
| |
| | 1.96E+02
| |
| | 1.74E+02
| |
| | 2.19E+02
| |
| | ※1 同上
| |
| |-
| |
| | 155
| |
| | 9.00E+02
| |
| | 8.78E+02
| |
| | 5.34E+02
| |
| | 2.59E+01
| |
| | 1.28E+01
| |
| | 6.44E+01
| |
| | 8.74E+02
| |
| | 8.52E+02
| |
| | 5.08E+02
| |
| | ※1 同上
| |
| |-
| |
| | 156
| |
| | 5.45E+02
| |
| | 9.00E+02
| |
| | 2.23E+03
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 4.45E+01
| |
| | 5.34E+02
| |
| | 8.89E+02
| |
| | 2.22E+03
| |
| | ※40 m/Z=156, 158, 160では、安定同位体として、GdとDyのみが存在し、他m/ZでDyの検出が認められないため、Gdと同定。
| |
| |-
| |
| | 157
| |
| | 2.45E+02
| |
| | 7.78E+01
| |
| | 1.00E+02
| |
| | 3.70E+00
| |
| | 6.42E+00
| |
| | 2.30E+01
| |
| | 2.41E+02
| |
| | 7.41E+01
| |
| | 9.63E+01
| |
| | ※1 同上
| |
| |-
| |
| | 158
| |
| | 7.78E+01
| |
| | 1.09E+03
| |
| | 2.10E+03
| |
| | 1.48E+01
| |
| | 1.70E+01
| |
| | 6.58E+01
| |
| | 6.30E+01
| |
| | 1.07E+03
| |
| | 2.09E+03
| |
| | ※40 同上
| |
| |-
| |
| | 159
| |
| | 5.56E+01
| |
| | 8.89E+01
| |
| | 7.78E+01
| |
| | 7.41E+00
| |
| | 6.42E+00
| |
| | 2.67E+01
| |
| | 4.82E+01
| |
| | 8.15E+01
| |
| | 7.04E+01
| |
| | ※1 同上
| |
| |-
| |
| | 160
| |
| | 3.33E+01
| |
| | 7.56E+02
| |
| | 1.24E+03
| |
| | 1.11E+01
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 7.45E+02
| |
| | 1.23E+03
| |
| | ※40 同上
| |
| |-
| |
| |}
| |
| | |
| | |
| | |
| | |
| {| class="wikitable"
| |
| |+表 ICP-MS定性分析での各質量数の計数率一覧表(2PEN2101、2PEN2102)(5/6)
| |
| !rowspan="2"|質量数(m/Z)
| |
| !colspan="3"|試料測定データ ①計数率 [cps]
| |
| !colspan="3"|ブランク液 測定データ計数率 [cps]
| |
| !colspan="3"|正味計数率 ①-②[cps]
| |
| !rowspan="2"|備考
| |
| |-
| |
| !操作ブランク
| |
| !2PEN2101
| |
| !2PEN2102
| |
| !ブランク液平均 ②μ
| |
| !ブランク液標準偏差σ
| |
| !検出限界(DL)μ+3σ
| |
| !操作ブランク
| |
| !2PEN2101
| |
| !2PEN2102
| |
| |-
| |
| | 161
| |
| | 4.45E+01
| |
| | 4.45E+01
| |
| | 1.11E+01
| |
| | 7.41E+00
| |
| | 6.42E+00
| |
| | 2.67E+01
| |
| | 3.70E+01
| |
| | 3.70E+01
| |
| | <DL
| |
| |
| |
| |-
| |
| | 162
| |
| | 3.33E+01
| |
| | 5.56E+01
| |
| | 3.34E+01
| |
| | 3.71E+00
| |
| | 6.42E+00
| |
| | 2.30E+01
| |
| | 2.96E+01
| |
| | 5.19E+01
| |
| | 2.96E+01
| |
| | ※1 同上
| |
| |-
| |
| | 163
| |
| | 3.33E+01
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 7.41E+00
| |
| | 6.42E+00
| |
| | 2.67E+01
| |
| | 2.59E+01
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 164
| |
| | 1.11E+01
| |
| | 8.89E+01
| |
| | 2.22E+01
| |
| | 1.48E+01
| |
| | 1.70E+01
| |
| | 6.58E+01
| |
| | <DL
| |
| | 7.41E+01
| |
| | <DL
| |
| | ※41 m/Z=164では、安定同位体として、DyとErのみが存在し、軽希土類元素の酸化物や水酸化物の可能性もあり、そのいずれかと同定。
| |
| |-
| |
| | 165
| |
| | 2.22E+01
| |
| | 2.22E+01
| |
| | 4.45E+01
| |
| | 2.59E+01
| |
| | 6.42E+00
| |
| | 4.52E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 166
| |
| | 3.33E+01
| |
| | 3.33E+01
| |
| | 0.00E+00
| |
| | 2.22E+01
| |
| | 1.93E+01
| |
| | 8.00E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 167
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 1.85E+01
| |
| | 1.28E+01
| |
| | 5.70E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 168
| |
| | 2.22E+01
| |
| | 2.22E+01
| |
| | 2.22E+01
| |
| | 7.41E+00
| |
| | 1.28E+01
| |
| | 4.59E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 169
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 5.56E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 170
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 2.59E+01
| |
| | 1.28E+01
| |
| | 6.44E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 171
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 172
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 4.45E+01
| |
| | 1.48E+01
| |
| | 6.42E+00
| |
| | 3.41E+01
| |
| | <DL
| |
| | <DL
| |
| | 2.96E+01
| |
| | ※42 m/Z=172-175は、Gdの酸化物や水酸化物と同じm/Zであり、正味計数率の比も妥当であるため、Gdの酸化物または水酸化物と同定。
| |
| |-
| |
| | 173
| |
| | 2.22E+01
| |
| | 5.56E+01
| |
| | 2.22E+01
| |
| | 3.71E+00
| |
| | 6.42E+00
| |
| | 2.30E+01
| |
| | <DL
| |
| | 5.19E+01
| |
| | <DL
| |
| |
| |
| |-
| |
| | 174
| |
| | 1.11E+01
| |
| | 7.78E+01
| |
| | 0.00E+00
| |
| | 1.48E+01
| |
| | 1.28E+01
| |
| | 5.33E+01
| |
| | <DL
| |
| | 6.30E+01
| |
| | <DL
| |
| |
| |
| |-
| |
| | 175
| |
| | 4.45E+01
| |
| | 5.56E+01
| |
| | 8.89E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 4.45E+01
| |
| | <DL
| |
| | 4.45E+01
| |
| | 7.78E+01
| |
| |
| |
| |-
| |
| | 176
| |
| | 3.33E+01
| |
| | 3.33E+01
| |
| | 2.22E+01
| |
| | 2.59E+01
| |
| | 6.42E+00
| |
| | 4.52E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 177
| |
| | 1.11E+02
| |
| | 1.00E+02
| |
| | 2.22E+01
| |
| | 5.56E+01
| |
| | 7.78E+01
| |
| | 2.89E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 178
| |
| | 3.45E+02
| |
| | 6.67E+01
| |
| | 4.45E+01
| |
| | 7.78E+01
| |
| | 1.16E+02
| |
| | 4.24E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 179
| |
| | 1.11E+02
| |
| | 4.45E+01
| |
| | 3.33E+01
| |
| | 7.04E+01
| |
| | 7.40E+01
| |
| | 2.92E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 180
| |
| | 7.56E+02
| |
| | 8.89E+01
| |
| | 8.89E+01
| |
| | 2.37E+02
| |
| | 2.10E+02
| |
| | 8.68E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 181
| |
| | 7.34E+02
| |
| | 1.06E+03
| |
| | 7.67E+02
| |
| | 1.85E+01
| |
| | 1.28E+01
| |
| | 5.70E+01
| |
| | 7.15E+02
| |
| | 1.04E+03
| |
| | 7.48E+02
| |
| | ※1 同上
| |
| |-
| |
| | 182
| |
| | 1.64E+05
| |
| | 5.60E+03
| |
| | 2.43E+04
| |
| | 4.04E+04
| |
| | 2.04E+04
| |
| | 1.02E+05
| |
| | 1.24E+05
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 183
| |
| | 5.36E+04
| |
| | 2.55E+03
| |
| | 2.85E+03
| |
| | 1.28E+04
| |
| | 4.28E+03
| |
| | 2.57E+04
| |
| | 4.08E+04
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 184
| |
| | 3.08E+04
| |
| | 6.23E+03
| |
| | 1.07E+04
| |
| | 1.25E+04
| |
| | 3.98E+03
| |
| | 2.45E+04
| |
| | 1.82E+04
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 185
| |
| | 0.00E+00
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 7.41E+00
| |
| | 6.42E+00
| |
| | 2.67E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 186
| |
| | 8.73E+04
| |
| | 1.60E+04
| |
| | 5.53E+03
| |
| | 1.18E+04
| |
| | 6.04E+03
| |
| | 2.99E+04
| |
| | 7.55E+04
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 187
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 1.48E+01
| |
| | 1.70E+01
| |
| | 6.58E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 188
| |
| | 2.22E+01
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 7.41E+00
| |
| | 6.42E+00
| |
| | 2.67E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 189
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 3.71E+00
| |
| | 6.42E+00
| |
| | 2.30E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 190
| |
| | 2.22E+01
| |
| | 2.22E+01
| |
| | 0.00E+00
| |
| | 0.00E+00
| |
| | 0.00E+00
| |
| | 0.00E+00
| |
| | 2.22E+01
| |
| | 2.22E+01
| |
| | <DL
| |
| | ※1 同上
| |
| |-
| |
| | 191
| |
| | 2.22E+01
| |
| | 4.45E+01
| |
| | 1.11E+01
| |
| | 4.08E+01
| |
| | 1.70E+01
| |
| | 9.17E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 192
| |
| | 7.78E+01
| |
| | 0.00E+00
| |
| | 2.22E+01
| |
| | 3.71E+00
| |
| | 6.42E+00
| |
| | 2.30E+01
| |
| | 7.41E+01
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 193
| |
| | 1.11E+02
| |
| | 4.45E+01
| |
| | 5.56E+01
| |
| | 1.41E+02
| |
| | 6.12E+01
| |
| | 3.24E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 194
| |
| | 1.01E+03
| |
| | 8.89E+01
| |
| | 4.45E+01
| |
| | 2.22E+01
| |
| | 1.92E-03
| |
| | 2.22E+01
| |
| | 9.89E+02
| |
| | 6.67E+01
| |
| | 2.22E+01
| |
| | ※1 同上
| |
| |-
| |
| | 195
| |
| | 9.89E+02
| |
| | 1.45E+02
| |
| | 3.33E+01
| |
| | 1.48E+01
| |
| | 6.42E+00
| |
| | 3.41E+01
| |
| | 9.74E+02
| |
| | 1.30E+02
| |
| | <DL
| |
| | ※1 同上
| |
| |-
| |
| | 196
| |
| | 7.11E+02
| |
| | 8.89E+01
| |
| | 8.89E+01
| |
| | 2.22E+01
| |
| | 2.94E+01
| |
| | 1.10E+02
| |
| | 6.89E+02
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 197
| |
| | 2.85E+03
| |
| | 1.06E+03
| |
| | 8.89E+02
| |
| | 1.90E+03
| |
| | 2.92E+03
| |
| | 1.07E+04
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 198
| |
| | 1.74E+03
| |
| | 2.78E+02
| |
| | 2.45E+02
| |
| | 4.00E+02
| |
| | 1.76E+02
| |
| | 9.29E+02
| |
| | 1.34E+03
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 199
| |
| | 6.67E+02
| |
| | 5.22E+02
| |
| | 2.78E+02
| |
| | 5.11E+02
| |
| | 5.31E+02
| |
| | 2.10E+03
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 200
| |
| | 1.13E+03
| |
| | 5.89E+02
| |
| | 4.67E+02
| |
| | 8.99E+02
| |
| | 5.79E+02
| |
| | 2.64E+03
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 201
| |
| | 4.34E+02
| |
| | 2.67E+02
| |
| | 2.56E+02
| |
| | 3.59E+02
| |
| | 3.72E+02
| |
| | 1.48E+03
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 202
| |
| | 1.74E+03
| |
| | 1.32E+03
| |
| | 5.45E+02
| |
| | 8.74E+02
| |
| | 7.92E+02
| |
| | 3.25E+03
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 203
| |
| | 1.78E+02
| |
| | 8.89E+01
| |
| | 4.45E+01
| |
| | 4.08E+01
| |
| | 1.28E+01
| |
| | 7.93E+01
| |
| | 1.37E+02
| |
| | 4.82E+01
| |
| | <DL
| |
| | ※1 同上
| |
| |-
| |
| | 204
| |
| | 3.33E+02
| |
| | 1.19E+04
| |
| | 9.34E+02
| |
| | 3.96E+02
| |
| | 3.15E+02
| |
| | 1.34E+03
| |
| | <DL
| |
| | 1.15E+04
| |
| | <DL
| |
| | ※43 m/Z=204,206,207,208での正味計数率の比が、Pbの天然同位体組成に近いため、Pbと同定。
| |
| |-
| |
| | 205
| |
| | 3.00E+02
| |
| | 2.56E+02
| |
| | 2.11E+02
| |
| | 1.15E+02
| |
| | 1.12E+02
| |
| | 4.52E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 206
| |
| | 2.80E+03
| |
| | 2.08E+05
| |
| | 1.37E+04
| |
| | 2.15E+03
| |
| | 4.83E+02
| |
| | 3.60E+03
| |
| | <DL
| |
| | 2.06E+05
| |
| | 1.16E+04
| |
| | ※43 同上
| |
| |-
| |
| | 207
| |
| | 2.87E+03
| |
| | 1.79E+05
| |
| | 1.14E+04
| |
| | 1.68E+03
| |
| | 4.01E+02
| |
| | 2.89E+03
| |
| | <DL
| |
| | 1.78E+05
| |
| | 9.75E+03
| |
| | ※43 同上
| |
| |-
| |
| | 208
| |
| | 6.10E+03
| |
| | 4.22E+05
| |
| | 2.64E+04
| |
| | 4.22E+03
| |
| | 1.39E+03
| |
| | 8.40E+03
| |
| | <DL
| |
| | 4.17E+05
| |
| | 2.22E+04
| |
| | ※43 同上
| |
| |-
| |
| | 209
| |
| | 8.89E+01
| |
| | 3.00E+02
| |
| | 1.78E+02
| |
| | 4.45E+01
| |
| | 4.45E+01
| |
| | 1.78E+02
| |
| | <DL
| |
| | 2.56E+02
| |
| | <DL
| |
| | ※44 m/Z=209では、安定同位体として、Biのみが存在するため、Biと同定。
| |
| |-
| |
| | 210
| |
| | 0.00E+00
| |
| | 0.00E+00
| |
| | 4.45E+01
| |
| | 1.11E+01
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | <DL
| |
| | <DL
| |
| | 3.34E+01
| |
| | ※45 適切な核種や妨害イオンが想定されず、正味計数率も低いことからノイズと同定。
| |
| |-
| |
| |}
| |
| | |
| | |
| | |
| {| class="wikitable"
| |
| |+表 ICP-MS定性分析での各質量数の計数率一覧表(2PEN2101、2PEN2102)(6/6)
| |
| !rowspan="2"|質量数(m/Z)
| |
| !colspan="3"|試料測定データ ①計数率 [cps]
| |
| !colspan="3"|ブランク液 測定データ計数率 [cps]
| |
| !colspan="3"|正味計数率 ①-②[cps]
| |
| !rowspan="2"|備考
| |
| |-
| |
| !操作ブランク
| |
| !2PEN2101
| |
| !2PEN2102
| |
| !ブランク液平均 ②μ
| |
| !ブランク液標準偏差σ
| |
| !検出限界(DL)μ+3σ
| |
| !操作ブランク
| |
| !2PEN2101
| |
| !2PEN2102
| |
| |-
| |
| | 211
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 4.45E+01
| |
| | 3.71E+00
| |
| | 6.42E+00
| |
| | 2.30E+01
| |
| | <DL
| |
| | <DL
| |
| | 4.08E+01
| |
| |
| |
| |-
| |
| | 212
| |
| | 2.22E+01
| |
| | 3.33E+01
| |
| | 0.00E+00
| |
| | 1.48E+01
| |
| | 2.57E+01
| |
| | 9.18E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 213
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 0.00E+00
| |
| | 2.59E+01
| |
| | 6.42E+00
| |
| | 4.52E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 214
| |
| | 3.33E+01
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 5.56E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 215
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 1.85E+01
| |
| | 6.42E+00
| |
| | 3.78E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 216
| |
| | 2.22E+01
| |
| | 3.33E+01
| |
| | 3.34E+01
| |
| | 7.41E+00
| |
| | 1.28E+01
| |
| | 4.59E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 217
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 7.41E+00
| |
| | 6.42E+00
| |
| | 2.67E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 218
| |
| | 2.22E+01
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 4.45E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 219
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 1.48E+01
| |
| | 6.42E+00
| |
| | 3.41E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 220
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 0.00E+00
| |
| | 3.71E+00
| |
| | 6.42E+00
| |
| | 2.30E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 221
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 7.41E+00
| |
| | 6.42E+00
| |
| | 2.67E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 222
| |
| | 3.33E+01
| |
| | 2.22E+01
| |
| | 0.00E+00
| |
| | 7.41E+00
| |
| | 6.42E+00
| |
| | 2.67E+01
| |
| | 2.59E+01
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 223
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 2.22E+01
| |
| | 2.59E+01
| |
| | 1.28E+01
| |
| | 6.45E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 224
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 0.00E+00
| |
| | 3.71E+00
| |
| | 6.42E+00
| |
| | 2.30E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 225
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 0.00E+00
| |
| | 0.00E+00
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | ※1 同上
| |
| |-
| |
| | 226
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 4.45E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 227
| |
| | 3.33E+01
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 1.85E+01
| |
| | 1.28E+01
| |
| | 5.70E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 228
| |
| | 0.00E+00
| |
| | 2.22E+01
| |
| | 0.00E+00
| |
| | 1.48E+01
| |
| | 1.70E+01
| |
| | 6.58E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 229
| |
| | 2.22E+01
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 4.45E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 230
| |
| | 0.00E+00
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 7.41E+00
| |
| | 6.42E+00
| |
| | 2.67E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 231
| |
| | 3.34E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 7.41E+00
| |
| | 1.28E+01
| |
| | 4.59E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 232
| |
| | 1.00E+02
| |
| | 1.33E+02
| |
| | 8.89E+01
| |
| | 3.33E+01
| |
| | 5.78E+01
| |
| | 2.07E+02
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 233
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 3.34E+01
| |
| | 3.71E+00
| |
| | 6.42E+00
| |
| | 2.30E+01
| |
| | <DL
| |
| | <DL
| |
| | 2.97E+01
| |
| | ※46 m/Z=233, 234, 235, 236, 238では、安定同位体は存在せず、使用済燃料中に含まれる主な核種がUであるため、Uと同定。
| |
| |-
| |
| | 234
| |
| | 0.00E+00
| |
| | 1.00E+02
| |
| | 1.22E+02
| |
| | 2.59E+01
| |
| | 2.31E+01
| |
| | 9.54E+01
| |
| | <DL
| |
| | 7.41E+01
| |
| | 9.63E+01
| |
| |
| |
| |-
| |
| | 235
| |
| | 1.11E+01
| |
| | 2.96E+03
| |
| | 4.85E+03
| |
| | 3.71E+01
| |
| | 6.41E+00
| |
| | 5.63E+01
| |
| | <DL
| |
| | 2.92E+03
| |
| | 4.81E+03
| |
| |
| |
| |-
| |
| | 236
| |
| | 0.00E+00
| |
| | 6.56E+02
| |
| | 8.23E+02
| |
| | 2.59E+01
| |
| | 1.28E+01
| |
| | 6.44E+01
| |
| | <DL
| |
| | 6.30E+02
| |
| | 7.97E+02
| |
| |
| |
| |-
| |
| | 237
| |
| | 1.11E+01
| |
| | 5.56E+01
| |
| | 1.67E+02
| |
| | 7.41E+00
| |
| | 1.28E+01
| |
| | 4.59E+01
| |
| | <DL
| |
| | 4.82E+01
| |
| | 1.59E+02
| |
| | ※47 m/Z=237では、安定同位体は存在せず、使用済燃料中に含まれる主な核種がNpであるため、Npと同定。
| |
| |-
| |
| | 238
| |
| | 1.33E+02
| |
| | 1.64E+05
| |
| | 2.69E+05
| |
| | 2.48E+02
| |
| | 1.62E+02
| |
| | 7.34E+02
| |
| | <DL
| |
| | 1.64E+05
| |
| | 2.69E+05
| |
| | ※46 同上
| |
| |-
| |
| | 239
| |
| | 5.56E+01
| |
| | 8.11E+02
| |
| | 1.26E+03
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 4.45E+01
| |
| | 4.45E+01
| |
| | 8.00E+02
| |
| | 1.25E+03
| |
| | ※48 m/Z=239, 240, 242では、安定同位体は存在せず、使用済燃料中に含まれる主な核種がPuであるため、Puと同定。
| |
| |-
| |
| | 240
| |
| | 2.22E+01
| |
| | 1.67E+02
| |
| | 4.56E+02
| |
| | 1.48E+01
| |
| | 6.42E+00
| |
| | 3.41E+01
| |
| | <DL
| |
| | 1.52E+02
| |
| | 4.41E+02
| |
| | ※48 同上
| |
| |-
| |
| | 241
| |
| | 1.11E+01
| |
| | 1.56E+02
| |
| | 1.44E+02
| |
| | 1.48E+01
| |
| | 6.42E+00
| |
| | 3.41E+01
| |
| | <DL
| |
| | 1.41E+02
| |
| | 1.30E+02
| |
| | ※49 m/Z=241では、安定同位体は存在せず、使用済燃料中に含まれる主な核種がPuとAmであるため、PuまたはAmと同定。
| |
| |-
| |
| | 242
| |
| | 3.33E+01
| |
| | 2.22E+01
| |
| | 7.78E+01
| |
| | 3.71E+00
| |
| | 6.42E+00
| |
| | 2.30E+01
| |
| | 2.96E+01
| |
| | <DL
| |
| | 7.41E+01
| |
| |
| |
| |-
| |
| | 243
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 5.56E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 244
| |
| | 2.22E+01
| |
| | 4.45E+01
| |
| | 3.33E+01
| |
| | 1.85E+01
| |
| | 1.28E+01
| |
| | 5.70E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 245
| |
| | 3.33E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 3.71E+00
| |
| | 6.42E+00
| |
| | 2.30E+01
| |
| | 2.96E+01
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 246
| |
| | 0.00E+00
| |
| | 0.00E+00
| |
| | 0.00E+00
| |
| | 1.48E+01
| |
| | 6.42E+00
| |
| | 3.41E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 247
| |
| | 0.00E+00
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 3.71E+00
| |
| | 6.42E+00
| |
| | 2.30E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 248
| |
| | 2.22E+01
| |
| | 0.00E+00
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 1.93E+01
| |
| | 8.00E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 249
| |
| | 1.11E+01
| |
| | 2.22E+01
| |
| | 0.00E+00
| |
| | 3.33E+01
| |
| | 1.93E+01
| |
| | 9.11E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| | 250
| |
| | 2.22E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 1.11E+01
| |
| | 4.45E+01
| |
| | <DL
| |
| | <DL
| |
| | <DL
| |
| |
| |
| |-
| |
| |}
| |
| | |
| | |
| | |
| | |
|
| |
|
| [[Gr1:分析方法(JAEA 2021年度)|分析方法(測定方法、不確かさ評価、定量下限値)はこちら]] | | ==定性分析結果== |
| | : 定性分析結果を別ページ[[Results of ICP-MS-2021-JAEA#定性分析結果|ICP-MS測定結果(JAEA 2021年度 受入サンプル共通)]]に示した。 |
| | : 2PEN2101では、Fe、Al、Pb、Zn、Sb、U、Ca、Cu、Zr、Mn、Ni、Sn、Mo、V、Y、Gd、Pu、Np、Sr、Pr、Ag、Nd、Pd、Rh、Bi、As、Sm、Cdの計28元素が検出された。 |