|
|
| (2人の利用者による、間の26版が非表示) |
| 1行目: |
1行目: |
| {{DISPLAYTITLE:2PEN2101 ICP-MS}} | | {{DISPLAYTITLE:2号機X-6ペネ調査装置付着物-1（2PEN2101）／ICP-MS}} |
| {| class="wikitable sortable mw-collapsible mw-collapsed" | | {| class="wikitable mw-collapsible mw-collapsed" |
| |+更新履歴 | | |+更新履歴 |
| !width="30pt"|No | | !width="30pt"|No |
| 7行目: |
7行目: |
| !width="500pt"|内容 | | !width="500pt"|内容 |
| !width="200pt"|備考 | | !width="200pt"|備考 |
| !width="100pt"|記載者
| |
| |- | | |- |
| |1 | | |1 |
| |2022/04/25 | | |2025/3/6 |
| |新規 | | |新規 |
| |2PEN2101 ICP-MS分析結果の登録（IRID報告書より転記）。 | | |ICP-MS分析結果の掲載（出典<ref name="JAEA23a">令和3年度福島第一原子力発電所の炉内付着物サンプル等の分析，日本原子力研究開発機構，JAEA-Data/Code 2023-005．</ref>） |
| |
| | |旧ページは [[Gr1:2PEN2101(2021)ICPMS|こちら（アクセス限定：Gr1）]] |
| |原稿作成：佐々木・大西(JAEA)<br>
| |
| wiki転記:池内(JAEA)
| |
| |-
| |
| |2
| |
| |2022/11/22
| |
| |承認 | |
| |
| |
| |不確かさ及び定量下限値の評価は[[Gr1:分析方法（JAEA 2021年度）|分析方法]]に移動した。
| |
| |池内(JAEA)
| |
| |-
| |
| |3
| |
| |2023/1/6
| |
| |改訂
| |
| |Zrの追加分析結果の追記に伴い、表の連番を修正した。
| |
| |
| |
| |池内(JAEA)
| |
| |}
| |
| | |
| (1)定量分析結果
| |
| 元の試料溶液中における定量分析対象核種重量 [ng] を表(共通)-1に示す。溶解した試料重量あたりの定量分析対象核種重量 [ng/g] を表(共通)-2に示す。各核種の重量表(共通)-1から求めた各元素の同位体比を表(共通)-3に示す。参考として、各元素の天然同位体組成[19]から質量比に換算した同位体比を併記している。
| |
| Cr、Fe、Ni、Mo、Ndについては、天然同位体組成に近い同位体比であった。Uについては、U-234、U-235、U-236、U-238が検出され、U-235/U-238の同位体比（0.0200±0.0006）は天然同位体比（0.0072）よりも高い値を示しており、燃料由来であることが示唆された。
| |
| | |
| {| class="wikitable"
| |
| |+表(共通)-1 ICP-MS定量分析結果（溶解液中の核種重量）
| |
| |試料
| |
| |Li-6 [ng]
| |
| |Li-7 [ng]
| |
| |B-10 [ng]
| |
| |B-11 [ng]
| |
| |Cr-52 [ng]
| |
| |Cr-53 [ng]
| |
| |Fe-56 [ng]
| |
| |Fe-57 [ng]
| |
| |Ni-60 [ng]
| |
| |Ni-61 [ng]
| |
| |Ni-62 [ng]
| |
| |Zr-90 [ng]
| |
| |Zr-91 [ng]
| |
| |Mo-95 [ng]
| |
| |Mo-97 [ng]
| |
| |Mo-98 [ng]
| |
| |Ag-107 [ng]
| |
| |Ag-109 [ng]
| |
| |Cs-133 [ng]
| |
| |Nd-143 [ng]
| |
| |Nd-145 [ng]
| |
| |Nd-146 [ng]
| |
| |U-234 [ng]
| |
| |U-235 [ng]
| |
| |U-236 [ng]
| |
| |U-238 [ng]
| |
| |-
| |
| |2PEN2101
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |5E+02 ± 1E+02
| |
| |5.1E+01 ± 2E+00
| |
| |1.10E+04 ± 3E+02
| |
| |2.4E+02 ± 1E+01
| |
| |1.08E+02 ± 1E+00
| |
| |5.3E+00 ± 8E-01
| |
| |1.35E+01 ± 8E-01
| |
| |1.38E+02 ± 1E+00
| |
| |3.4E+01 ± 3E+00
| |
| |4.3E+00 ± 5E-01
| |
| |3.17E+00 ± 7E-02
| |
| |7.2E+00 ± 2E-01
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |5.7E-01 ± 9E-02
| |
| |4E-01 ± 3E-01
| |
| |9E-01 ± 1E-01
| |
| |2E-01 ± 2E-01
| |
| |1.49E+01 ± 2E-01
| |
| |2.7E+00 ± 2E-01
| |
| |7.45E+02 ± 6E+00
| |
| |-
| |
| |2PEN2102
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |6.9E+03 ± 3E+02
| |
| |1.4E+02 ± 1E+01
| |
| |3.98E+01 ± 8E-01
| |
| |1.1E+00 ± 8E-01
| |
| |3.7E+00 ± 8E-01
| |
| |2.75E+02 ± 1E+00
| |
| |6.3E+01 ± 3E+00
| |
| |5.4E+00 ± 5E-01
| |
| |3.93E+00 ± 7E-02
| |
| |7.7E+00 ± 2E-01
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |1.12E+00 ± 9E-02
| |
| |5E-01 ± 3E-01
| |
| |9E-01 ± 1E-01
| |
| |4E-01 ± 2E-01
| |
| |2.56E+01 ± 2E-01
| |
| |4.5E+00 ± 2E-01
| |
| |1.33E+03 ± 1E+01
| |
| |-
| |
| |2WEL2101A
| |
| |＜LOQ
| |
| |3.31E+02 ± 2E+00
| |
| |1.04E+03 ± 1E+01
| |
| |4.0E+03 ± 1E+02
| |
| |3.42E+03 ± 6E+01
| |
| |3.79E+02 ± 1E+00
| |
| |2.35E+07 ± 1E+05
| |
| |5.23E+05 ± 1E+03
| |
| |5.00E+03 ± 1E+01
| |
| |2.11E+02 ± 1E+00
| |
| |6.91E+02 ± 1E+00
| |
| |1.81E+03 ± 1E+01
| |
| |3.91E+02 ± 3E+00
| |
| |6.8E+03 ± 1E+02
| |
| |6.73E+03 ± 8E+01
| |
| |8.70E+03 ± 1E+02
| |
| |2.94E+01 ± 3E-01
| |
| |2.7E+02 ± 2E+01
| |
| |4.58E+02 ± 5E+00
| |
| |5.47E+00 ± 9E-02
| |
| |4.0E+00 ± 3E-01
| |
| |5.8E+00 ± 1E-01
| |
| |2E+00 ± 2E+00
| |
| |1.68E+02 ± 2E+00
| |
| |2.6E+01 ± 2E+00
| |
| |8.05E+03 ± 6E+01
| |
| |-
| |
| |2WEL2101C
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |3.28E+02 ± 1E+00
| |
| |1.4E+03 ± 1E+02
| |
| |6.3E+02 ± 6E+01
| |
| |7.2E+01 ± 1E+00
| |
| |1.93E+06 ± 1E+04
| |
| |4.35E+04 ± 1E+02
| |
| |6.4E+02 ± 1E+01
| |
| |3.2E+01 ± 1E+00
| |
| |9.08E+01 ± 3E-01
| |
| |1.29E+02 ± 1E+00
| |
| |3.2E+01 ± 3E+00
| |
| |4.1E+02 ± 1E+01
| |
| |3.62E+02 ± 8E+00
| |
| |5.3E+02 ± 1E+01
| |
| |5.0E+00 ± 3E-01
| |
| |9.33E+01 ± 1E-01
| |
| |5.8E+01 ± 5E+00
| |
| |5.4E-01 ± 9E-02
| |
| |4E-01 ± 3E-01
| |
| |1.2E+00 ± 1E-01
| |
| |＜LOQ
| |
| |1.22E+01 ± 2E-01
| |
| |2.0E+00 ± 2E-01
| |
| |5.92E+02 ± 6E+00
| |
| |-
| |
| |2WEL2102A
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |7.35E+02 ± 1E+00
| |
| |2.9E+03 ± 1E+02
| |
| |7.57E+03 ± 6E+01
| |
| |8.30E+02 ± 1E+00
| |
| |5.27E+07 ± 1E+05
| |
| |1.17E+06 ± 1E+04
| |
| |4.28E+03 ± 1E+01
| |
| |1.75E+02 ± 1E+00
| |
| |5.71E+02 ± 1E+00
| |
| |<LOQ
| |
| |<LOQ
| |
| |1.5E+02 ± 1E+01
| |
| |9.6E+01 ± 8E+00
| |
| |2.4E+02 ± 1E+01
| |
| |1.30E+01 ± 3E-01
| |
| |1.24E+01 ± 1E-01
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |-
| |
| |2WEL2103A
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |2.87E+02 ± 1E+00
| |
| |1.1E+03 ± 1E+02
| |
| |5.2E+02 ± 6E+01
| |
| |6.4E+01 ± 1E+00
| |
| |1.07E+07 ± 1E+05
| |
| |2.31E+05 ± 3E+03
| |
| |1.54E+02 ± 1E+00
| |
| |6.6E+00 ± 8E-01
| |
| |2.24E+01 ± 8E-01
| |
| |<LOQ
| |
| |<LOQ
| |
| |6.8E+00 ± 5E-01
| |
| |3.52E+00 ± 7E-02
| |
| |1.10E+01 ± 2E-01
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |4E-01 ± 1E-01
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |-
| |
| |}
| |
| | |
| {| class="wikitable"
| |
| |+表(共通)-2 ICP-MS定量分析結果（溶液に移行した各試料単位重量あたりの核種重量）
| |
| |試料
| |
| |Li-6 [ng/g]
| |
| |Li-7 [ng/g]
| |
| |B-10 [ng/g]
| |
| |B-11 [ng/g]
| |
| |Cr-52 [ng/g]
| |
| |Cr-53 [ng/g]
| |
| |Fe-56 [ng/g]
| |
| |Fe-57 [ng/g]
| |
| |Ni-60 [ng/g]
| |
| |Ni-61 [ng/g]
| |
| |Ni-62 [ng/g]
| |
| |Zr-90 [ng/g]
| |
| |Zr-91 [ng/g]
| |
| |Mo-95 [ng/g]
| |
| |Mo-97 [ng/g]
| |
| |Mo-98 [ng/g]
| |
| |Ag-107 [ng/g]
| |
| |Ag-109 [ng/g] | |
| |Cs-133 [ng/g]
| |
| |Nd-143 [ng/g]
| |
| |Nd-145 [ng/g]
| |
| |Nd-146 [ng/g]
| |
| |U-234 [ng/g]
| |
| |U-235 [ng/g]
| |
| |U-236 [ng/g]
| |
| |U-238 [ng/g]
| |
| |-
| |
| |2PEN2101
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |8E+03 ± 2E+03
| |
| |8.9E+02 ± 4E+01
| |
| |1.93E+05 ± 5E+03
| |
| |4.2E+03 ± 2E+02
| |
| |1.90E+03 ± 1E+01
| |
| |9E+01 ± 1E+01
| |
| |2.4E+02 ± 1E+01
| |
| |2.43E+03 ± 2E+01
| |
| |6.0E+02 ± 5E+01
| |
| |7.6E+01 ± 8E+00
| |
| |5.6E+01 ± 1E+00
| |
| |1.26E+02 ± 3E+00
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |1.0E+01 ± 2E+00
| |
| |6E+00 ± 5E+00
| |
| |1.6E+01 ± 2E+00
| |
| |4E+00 ± 3E+00
| |
| |2.62E+02 ± 3E+00
| |
| |4.7E+01 ± 3E+00
| |
| |1.31E+04 ± 1E+02
| |
| |-
| |
| |2PEN2102
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |2.00E+05 ± 8E+03
| |
| |4.2E+03 ± 3E+02
| |
| |1.16E+03 ± 2E+01
| |
| |3E+01 ± 2E+01
| |
| |1.1E+02 ± 2E+01
| |
| |8.00E+03 ± 4E+01
| |
| |1.84E+03 ± 9E+01
| |
| |1.6E+02 ± 1E+01
| |
| |1.14E+02 ± 2E+00
| |
| |2.24E+02 ± 5E+00
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |3.3E+01 ± 3E+00
| |
| |1.4E+01 ± 8E+00
| |
| |2.6E+01 ± 3E+00
| |
| |1.2E+01 ± 5E+00
| |
| |7.46E+02 ± 5E+00
| |
| |1.32E+02 ± 5E+00
| |
| |3.86E+04 ± 2E+02
| |
| |-
| |
| |2WEL2101A
| |
| |＜LOQ
| |
| |9.45E+03 ± 7E+01
| |
| |2.97E+04 ± 1E+02
| |
| |1.13E+05 ± 3E+03
| |
| |9.8E+04 ± 2E+03
| |
| |1.08E+04 ± 1E+02
| |
| |6.71E+08 ± 1E+06
| |
| |1.50E+07 ± 1E+05
| |
| |1.43E+05 ± 1E+03
| |
| |6.04E+03 ± 3E+01
| |
| |1.98E+04 ± 1E+02
| |
| |5.17E+04 ± 4E+02
| |
| |1.12E+04 ± 1E+02
| |
| |1.95E+05 ± 3E+03
| |
| |1.92E+05 ± 2E+03
| |
| |2.49E+05 ± 4E+03
| |
| |8.40E+02 ± 8E+00
| |
| |7.7E+03 ± 6E+02
| |
| |1.31E+04 ± 1E+02
| |
| |1.56E+02 ± 3E+00
| |
| |1.16E+02 ± 8E+00
| |
| |1.67E+02 ± 3E+00
| |
| |6E+01 ± 5E+01
| |
| |4.81E+03 ± 5E+01
| |
| |7.6E+02 ± 5E+01
| |
| |2.30E+05 ± 2E+03
| |
| |-
| |
| |2WEL2101C
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |5.78E+04 ± 1E+02
| |
| |2.5E+05 ± 2E+04
| |
| |1.1E+05 ± 1E+04
| |
| |1.28E+04 ± 2E+02
| |
| |3.40E+08 ± 1E+06
| |
| |7.66E+06 ± 2E+04
| |
| |1.13E+05 ± 3E+03
| |
| |5.6E+03 ± 2E+02
| |
| |1.60E+04 ± 1E+02
| |
| |2.27E+04 ± 2E+02
| |
| |5.6E+03 ± 5E+02
| |
| |7.2E+04 ± 2E+03
| |
| |6.4E+04 ± 1E+03
| |
| |9.3E+04 ± 2E+03
| |
| |8.9E+02 ± 5E+01
| |
| |1.64E+04 ± 1E+02
| |
| |1.02E+04 ± 9E+02
| |
| |1.0E+02 ± 2E+01
| |
| |7E+01 ± 5E+01
| |
| |2.0E+02 ± 2E+01
| |
| |＜LOQ
| |
| |2.15E+03 ± 3E+01
| |
| |3.6E+02 ± 3E+01
| |
| |1.04E+05 ± 1E+03
| |
| |-
| |
| |2WEL2102A
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |1.18E+04 ± 1E+02
| |
| |4.7E+04 ± 2E+03
| |
| |1.21E+05 ± 1E+03
| |
| |1.33E+04 ± 1E+02
| |
| |8.45E+08 ± 2E+06
| |
| |1.88E+07 ± 1E+05
| |
| |6.87E+04 ± 2E+02
| |
| |2.80E+03 ± 2E+01
| |
| |9.16E+03 ± 1E+01
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |2.4E+03 ± 2E+02
| |
| |1.5E+03 ± 1E+02
| |
| |3.8E+03 ± 2E+02
| |
| |2.08E+02 ± 5E+00
| |
| |1.99E+02 ± 1E+00
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |-
| |
| |2WEL2103A
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |1.98E+04 ± 1E+02
| |
| |7.8E+04 ± 7E+03
| |
| |3.6E+04 ± 4E+03
| |
| |4.38E+03 ± 7E+01
| |
| |7.36E+08 ± 9E+06
| |
| |1.59E+07 ± 2E+05
| |
| |1.06E+04 ± 1E+02
| |
| |4.6E+02 ± 6E+01
| |
| |1.55E+03 ± 5E+01
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |4.7E+02 ± 3E+01
| |
| |2.43E+02 ± 4E+00
| |
| |7.6E+02 ± 1E+01
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |2.4E+01 ± 8E+00
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |＜LOQ
| |
| |-
| |
| |}
| |
| | |
| {| class="wikitable"
| |
| |+表（共通）-3 各元素の同位体比
| |
| !rowspan="2"|試料
| |
| !B
| |
| !Cr
| |
| !Fe
| |
| !colspan="2"|Ni
| |
| !Zr
| |
| !colspan="2"|Mo
| |
| !Ag
| |
| !colspan="2"|Nd
| |
| !U
| |
| |-
| |
| |(B-10/B-11)
| |
| |(Cr-53/Cr-52)
| |
| |(Fe-57/Fe-56)
| |
| |(Ni-61/Ni-60)
| |
| |(Ni-62/Ni-60)
| |
| |(Zr-91/Zr-90)
| |
| |(Mo-97/Mo-95)
| |
| |(Mo-98/Mo-95)
| |
| |(Ag-107/Ag-109)
| |
| |(Nd-143/Nd-146)
| |
| |(Nd-145/Nd-146)
| |
| |(U-235/U-238)
| |
| |-
| |
| |2PEN2101
| |
| |ー
| |
| |0.11±0.06
| |
| |0.022±0.002
| |
| |0.05±0.02
| |
| |0.13±0.01
| |
| |0.25±0.04
| |
| |0.7±0.2
| |
| |1.7±0.4
| |
| |ー
| |
| |0.6±0.3
| |
| |0.4±0.6
| |
| |0.0200±0.0006
| |
| |-
| |
| |2PEN2102
| |
| |ー
| |
| |ー
| |
| |0.021±0.004
| |
| |0.03±0.04
| |
| |0.09±0.04
| |
| |0.23±0.02
| |
| |0.7±0.1
| |
| |1.4±0.2
| |
| |ー
| |
| |1.3±0.4
| |
| |0.5±0.6
| |
| |0.0193±0.0003
| |
| |-
| |
| |2WEL2101A
| |
| |0.26±0.01
| |
| |0.111±0.004
| |
| |0.0223±0.0001
| |
| |0.0423±0.0005
| |
| |0.1383±0.0008
| |
| |0.216±0.004
| |
| |0.99±0.04
| |
| |1.27±0.06
| |
| |0.11±0.02
| |
| |0.94±0.05
| |
| |0.7±0.1
| |
| |0.0209±0.0006
| |
| |-
| |
| |2WEL2101C
| |
| |0.23±0.03
| |
| |0.11±0.02
| |
| |0.0225±0.0001
| |
| |0.049±0.004
| |
| |0.141±0.006
| |
| |0.25±0.05
| |
| |0.89±0.06
| |
| |1.3±0.1
| |
| |0.054±0.006
| |
| |0.5±0.2
| |
| |0.3±0.5
| |
| |0.0206±0.0008
| |
| |-
| |
| |2WEL2102A
| |
| |0.25±0.02
| |
| |0.110±0.002
| |
| |0.0223±0.0002
| |
| |0.0408±0.0005
| |
| |0.134±0.001
| |
| |ー
| |
| |0.64±0.1
| |
| |1.6±0.3
| |
| |1.04±0.05
| |
| |ー
| |
| |ー
| |
| |ー
| |
| |-
| |
| |2WEL2103A
| |
| |0.25±0.05
| |
| |0.12±0.03
| |
| |0.0216±0.0008
| |
| |0.04±0.01
| |
| |0.15±0.01
| |
| |ー
| |
| |0.51±0.07
| |
| |1.6±0.2
| |
| |ー
| |
| |ー
| |
| |ー
| |
| |ー
| |
| |-
| |
| |天然同位体比
| |
| |0.23
| |
| |0.116
| |
| |0.0235
| |
| |0.0442
| |
| |0.1432
| |
| |0.221
| |
| |0.62
| |
| |1.58
| |
| |1.06
| |
| |0.69
| |
| |0.48
| |
| |0.0072
| |
| |} | | |} |
|
| |
|
| (2)定性分析結果
| | ==定量分析結果== |
| 全質量数スキャンにより得られた各質量数における計数率と正味計数率、及び核種の判定結果を、2PEN2102の結果と合わせて表5.1-12に示す。
| | : 定量分析結果を別ページ[[Results of ICP-MS-2021-JAEA#定量分析結果|ICP-MS測定結果（JAEA 2021年度 受入サンプル共通）]]に示した。 |
| 2PEN2101では、Fe、Al、Pb、Zn、Sb、U、Ca、Cu、Zr、Mn、Ni、Sn、Mo、V、Y、Gd、Pu、Np、Sr、Pr、Ag、Nd、Pd、Rh、Bi、As、Sm、Cdの計28元素が検出された。
| | : 2PEN2101では、Cr、Fe、Ni、Mo、Ndについては、天然同位体組成に近い同位体比であった。Uについては、U-234、U-235、U-236、U-238が検出され、U-235/U-238の同位体比（0.0200±0.0006）は天然同位体比（0.0072）よりも高い値を示しており、燃料由来であることが示唆された。 |
|
| |
|
| [[Gr1:分析方法（JAEA 2021年度）|分析方法（測定方法、不確かさ評価、定量下限値）はこちら]] | | ==定性分析結果== |
| | : 定性分析結果を別ページ[[Results of ICP-MS-2021-JAEA#定性分析結果|ICP-MS測定結果（JAEA 2021年度 受入サンプル共通）]]に示した。 |
| | : 2PEN2101では、Fe、Al、Pb、Zn、Sb、U、Ca、Cu、Zr、Mn、Ni、Sn、Mo、V、Y、Gd、Pu、Np、Sr、Pr、Ag、Nd、Pd、Rh、Bi、As、Sm、Cdの計28元素が検出された。 |